Caterina Trotta , Pardeep Dahiya , Lorenzo Baldinelli , Gabriel Menendez Rodriguez , Priyanka Chakraborty , Giovanni Bistoni , Filippo De Angelis , Basker Sundararaju , Alceo Macchioni
{"title":"在磷酸盐缓冲水溶液中具有显著活性的氢进化反应钴分子催化剂","authors":"Caterina Trotta , Pardeep Dahiya , Lorenzo Baldinelli , Gabriel Menendez Rodriguez , Priyanka Chakraborty , Giovanni Bistoni , Filippo De Angelis , Basker Sundararaju , Alceo Macchioni","doi":"10.1039/d4cy00209a","DOIUrl":null,"url":null,"abstract":"<div><p>Herein, we show that [Cp*Co(2-ampy)I]I (2-ampy = 2-aminomethyl-pyridine) is an extremely active catalyst for HER, exhibiting a TOF of 109 000 s<sup>−1</sup> in phosphate buffered water solution (pH 7). The key to this remarkable activity stems from the establishment of a network of weak interactions in the second coordination sphere. As a matter of fact, both experimental and theoretical studies strongly suggest that the –NH<sub>2</sub> functionality of the 2-ampy ligand acts as an anchoring and orienting group for H<sub>2</sub>PO<sub>4</sub><sup>−</sup> through the establishment of an intermolecular hydrogen bonding with it that, in turn, intermolecularly donates a proton to Co–H liberating H<sub>2</sub>.</p></div>","PeriodicalId":66,"journal":{"name":"Catalysis Science & Technology","volume":null,"pages":null},"PeriodicalIF":4.4000,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/cy/d4cy00209a?page=search","citationCount":"0","resultStr":"{\"title\":\"A cobalt molecular catalyst for hydrogen evolution reaction with remarkable activity in phosphate buffered water solution†\",\"authors\":\"Caterina Trotta , Pardeep Dahiya , Lorenzo Baldinelli , Gabriel Menendez Rodriguez , Priyanka Chakraborty , Giovanni Bistoni , Filippo De Angelis , Basker Sundararaju , Alceo Macchioni\",\"doi\":\"10.1039/d4cy00209a\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Herein, we show that [Cp*Co(2-ampy)I]I (2-ampy = 2-aminomethyl-pyridine) is an extremely active catalyst for HER, exhibiting a TOF of 109 000 s<sup>−1</sup> in phosphate buffered water solution (pH 7). The key to this remarkable activity stems from the establishment of a network of weak interactions in the second coordination sphere. As a matter of fact, both experimental and theoretical studies strongly suggest that the –NH<sub>2</sub> functionality of the 2-ampy ligand acts as an anchoring and orienting group for H<sub>2</sub>PO<sub>4</sub><sup>−</sup> through the establishment of an intermolecular hydrogen bonding with it that, in turn, intermolecularly donates a proton to Co–H liberating H<sub>2</sub>.</p></div>\",\"PeriodicalId\":66,\"journal\":{\"name\":\"Catalysis Science & Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.4000,\"publicationDate\":\"2024-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.rsc.org/en/content/articlepdf/2024/cy/d4cy00209a?page=search\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis Science & Technology\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2044475324003162\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Science & Technology","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2044475324003162","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
A cobalt molecular catalyst for hydrogen evolution reaction with remarkable activity in phosphate buffered water solution†
Herein, we show that [Cp*Co(2-ampy)I]I (2-ampy = 2-aminomethyl-pyridine) is an extremely active catalyst for HER, exhibiting a TOF of 109 000 s−1 in phosphate buffered water solution (pH 7). The key to this remarkable activity stems from the establishment of a network of weak interactions in the second coordination sphere. As a matter of fact, both experimental and theoretical studies strongly suggest that the –NH2 functionality of the 2-ampy ligand acts as an anchoring and orienting group for H2PO4− through the establishment of an intermolecular hydrogen bonding with it that, in turn, intermolecularly donates a proton to Co–H liberating H2.
期刊介绍:
A multidisciplinary journal focusing on cutting edge research across all fundamental science and technological aspects of catalysis.
Editor-in-chief: Bert Weckhuysen
Impact factor: 5.0
Time to first decision (peer reviewed only): 31 days