控制用碱活性废物稳定膨润土-高岭土混合物膨胀行为的参数

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-06-04 DOI:10.28927/sr.2024.010023
Mariana Araújo, S. Ferrazzo, G. Bruschi, N. Consoli
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引用次数: 0

摘要

膨胀性土壤会对基础设施造成大规模破坏。使用硅酸盐水泥和石灰稳定土壤已被广泛用作解决这一问题的方法。然而,这些稳定剂都是不可再生的,而且能耗高。碱活性粘合剂是二氧化碳排放量较低的替代品。这项研究评估了使用甘蔗渣灰(SCBA)、水合蛋壳石灰(HEL)和氢氧化钠(NaOH)制成的碱活性粘合剂稳定膨胀性土壤的效果。自由膨胀试验和统计分析评估了干单位重量(12.5 和 14.5 kN/m3)、粘结剂(4 和 10%)、含水量(19.7 和 24.7%)和固化时间(0 和 7 天)对稳定混合物的影响。设计中采用了四因素因子设计,包括重复设计和中心点设计。为了更好地了解 NaOH 和 SCBA 对土壤膨胀的影响,还进行了其他测试。总的来说,所研究因素的增加会减少膨胀,尤其是粘结剂含量。但是,碱活性水泥的密度越高,膨胀性越大,两者之间并没有明显的相关性。碱性水泥的膨胀率分别从 13.8%(12.5 kN/m3 和 19.7% 湿度)和 8.8%(12.5 kN/m3 和 24.7% 湿度)降低到 7 天后的 2.5% 和 0%,粘结剂添加量为 10%。硅酸盐水泥的膨胀率在 7 天和添加 4% 粘结剂后分别从 13.8% (10.2 kN/m3 和 22.5% 水分)和 12.5% (10.2 kN/m3 和 27.5% 水分)降至 1.8% 和 1%。含 NaOH 的样品的膨胀率低于仅用水模塑的样品。最后,替代粘结剂可能是替代硅酸盐水泥进行膨胀控制的一种可行选择。
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Parameters controlling the expansive behavior of bentonite-kaolin mixtures stabilized with alkali-activated waste
Expansive soils can cause large-scale damage to the infrastructure. Soil stabilization with Portland cement and lime has been widely utilized as a solution to this problem. However, these stabilizers are non-renewable and energy-intensive. Alkali-activated binders are alternatives with lower carbon dioxide emissions. This research evaluated an expansive soil stabilization with an alkali-activated binder produced from sugarcane bagasse ash (SCBA), hydrated eggshell lime (HEL) and sodium hydroxide (NaOH). Free-swelling tests alongside a statistical analysis evaluated the influence of dry unit weight (12.5 and 14.5 kN/m3), binder (4 and 10%) and moisture content (19.7 and 24.7%) and curing time (0 and 7 days) on the stabilized mixtures. A four factors factorial design with duplicates and central points was outlined. To better understand the NaOH and SCBA influence over the soil expansion additional tests were performed. In general, an increase on the studied factors reduced swelling, especially binder content. However, the alkali-activated cement presented no clear correlation between higher density and higher expansion. Swell reduced from 13.8% (12.5 kN/m3 and 19.7% moisture) and 8.8% (12.5 kN/m3 and 24.7% moisture) to 2.5% and 0%, respectively, after 7 days and 10% binder addition for the alkaline cement. For Portland cement, swell reduced from 13.8% (10.2 kN/m3 and 22.5% moisture) and 12.5% (10.2 kN/m3 and 27.5% moisture) to 1.8% and 1%, respectively, after 7 days and 4% binder addition. Samples containing NaOH expanded less than samples molded with only water. Finally, the alternative binder might be a viable option to replace Portland cement for expansion control.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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