用于二氧化碳吸附的香港科技大学-1 整体石的一步法合成

IF 17.7 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-06-03 DOI:10.1093/chemle/upae109

Motomu Sakai, Ayaka Ito, Takaya Matsumoto, Masahiko Matsukata

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引用次数: 0

摘要

金属有机框架的广泛应用离不开成型技术。我们开发了一种一锅合成香港科技大学-1整体石的方法。在不添加金属源的情况下，通过在 1,3,5-苯三羧酸、乙醇和硝酸的水溶液中对铜单质进行水热处理，成功制备了 HKUST-1 单质。所制备的 HKUST-1 块体的二氧化碳吸附性能与市售的 HKUST-1 粉末状晶体相当。

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One-pot synthesis of HKUST-1 monolith for CO2 adsorption

Shape-forming technology is essential for the widespread utilization of metal-organic frameworks. We developed a one-pot synthesis method for HKUST-1 monolith. HKUST-1 monolith was successfully prepared by the hydrothermal treatment of a Cu monolith in an aqueous solution of 1,3,5-benzenetricarboxylic acid, ethanol, and nitric acid without the addition of a metal source. The prepared HKUST-1 monolith showed CO2 adsorption properties comparable to those of commercially available HKUST-1 powdery crystals.

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.