用于二氧化碳吸附的香港科技大学-1 整体石的一步法合成

IF 1.4 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Chemistry Letters Pub Date : 2024-06-03 DOI:10.1093/chemle/upae109
Motomu Sakai, Ayaka Ito, Takaya Matsumoto, Masahiko Matsukata
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引用次数: 0

摘要

金属有机框架的广泛应用离不开成型技术。我们开发了一种一锅合成香港科技大学-1整体石的方法。在不添加金属源的情况下,通过在 1,3,5-苯三羧酸、乙醇和硝酸的水溶液中对铜单质进行水热处理,成功制备了 HKUST-1 单质。所制备的 HKUST-1 块体的二氧化碳吸附性能与市售的 HKUST-1 粉末状晶体相当。
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One-pot synthesis of HKUST-1 monolith for CO2 adsorption
Shape-forming technology is essential for the widespread utilization of metal-organic frameworks. We developed a one-pot synthesis method for HKUST-1 monolith. HKUST-1 monolith was successfully prepared by the hydrothermal treatment of a Cu monolith in an aqueous solution of 1,3,5-benzenetricarboxylic acid, ethanol, and nitric acid without the addition of a metal source. The prepared HKUST-1 monolith showed CO2 adsorption properties comparable to those of commercially available HKUST-1 powdery crystals.
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来源期刊
Chemistry Letters
Chemistry Letters 化学-化学综合
CiteScore
3.00
自引率
6.20%
发文量
260
审稿时长
1.2 months
期刊介绍: Chemistry Letters covers the following topics: -Organic Chemistry- Physical Chemistry- Inorganic Chemistry- Analytical Chemistry- Materials Chemistry- Polymer Chemistry- Supramolecular Chemistry- Organometallic Chemistry- Coordination Chemistry- Biomolecular Chemistry- Natural Products and Medicinal Chemistry- Electrochemistry
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