Papa Aly Gueye , Lamine Yaffa , Dame Seye , Daouda Ndoye , Bocar Traoré , Mamadou Sidibé , Cheikh Abdoul Khadir Diop , Sergiu Shova , M. Weil (Editor)
{"title":"十钼酸八(二丁基铵)(VI)。","authors":"Papa Aly Gueye , Lamine Yaffa , Dame Seye , Daouda Ndoye , Bocar Traoré , Mamadou Sidibé , Cheikh Abdoul Khadir Diop , Sergiu Shova , M. Weil (Editor)","doi":"10.1107/S2414314624004632","DOIUrl":null,"url":null,"abstract":"<div><p>(C<sub>8</sub>H<sub>20</sub>N)<sub>8</sub>[Mo<sub>10</sub>O<sub>34</sub>] comprises a centrosymmetric decamolybdate polyanion linked through N—H⋯O hydrogen bonds to dibutylammonium counter-cations.</p></div><div><p>In the title salt, (C<sub>8</sub>H<sub>20</sub>N)<sub>8</sub>[Mo<sub>10</sub>O<sub>34</sub>], the [Mo<sub>10</sub>O<sub>34</sub>]<sup>8−</sup> polyanion is located about an inversion centre and can be considered as a <em>β</em>-type octamolybdate anion to which two additional MoO<sub>4</sub> tetrahedra are linked <em>via</em> common corners. The [Mo<sub>10</sub>O<sub>34</sub>]<sup>8−</sup> polyanions are packed in rows extending parallel to [001] and are connected to the dibutylammonium counter-cations through N—H⋯O hydrogen-bonding interactions. <span><figure><span><img><ol><li><span>Download : <span>Download high-res image (333KB)</span></span></li><li><span>Download : <span>Download full-size image</span></span></li></ol></span></figure></span> </p></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 5","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11151287/pdf/","citationCount":"0","resultStr":"{\"title\":\"Octakis(dibutylammonium) decamolybdate(VI)\",\"authors\":\"Papa Aly Gueye , Lamine Yaffa , Dame Seye , Daouda Ndoye , Bocar Traoré , Mamadou Sidibé , Cheikh Abdoul Khadir Diop , Sergiu Shova , M. Weil (Editor)\",\"doi\":\"10.1107/S2414314624004632\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>(C<sub>8</sub>H<sub>20</sub>N)<sub>8</sub>[Mo<sub>10</sub>O<sub>34</sub>] comprises a centrosymmetric decamolybdate polyanion linked through N—H⋯O hydrogen bonds to dibutylammonium counter-cations.</p></div><div><p>In the title salt, (C<sub>8</sub>H<sub>20</sub>N)<sub>8</sub>[Mo<sub>10</sub>O<sub>34</sub>], the [Mo<sub>10</sub>O<sub>34</sub>]<sup>8−</sup> polyanion is located about an inversion centre and can be considered as a <em>β</em>-type octamolybdate anion to which two additional MoO<sub>4</sub> tetrahedra are linked <em>via</em> common corners. The [Mo<sub>10</sub>O<sub>34</sub>]<sup>8−</sup> polyanions are packed in rows extending parallel to [001] and are connected to the dibutylammonium counter-cations through N—H⋯O hydrogen-bonding interactions. <span><figure><span><img><ol><li><span>Download : <span>Download high-res image (333KB)</span></span></li><li><span>Download : <span>Download full-size image</span></span></li></ol></span></figure></span> </p></div>\",\"PeriodicalId\":94324,\"journal\":{\"name\":\"IUCrData\",\"volume\":\"9 5\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-05-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11151287/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2414314624000488\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314624000488","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
(C8H20N)8[Mo10O34] comprises a centrosymmetric decamolybdate polyanion linked through N—H⋯O hydrogen bonds to dibutylammonium counter-cations.
In the title salt, (C8H20N)8[Mo10O34], the [Mo10O34]8− polyanion is located about an inversion centre and can be considered as a β-type octamolybdate anion to which two additional MoO4 tetrahedra are linked via common corners. The [Mo10O34]8− polyanions are packed in rows extending parallel to [001] and are connected to the dibutylammonium counter-cations through N—H⋯O hydrogen-bonding interactions.
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