{"title":"1-丁烯基共聚物中 4-苯基-1-丁烯和 4-芳基-1-丁烯共聚物所产生的非同寻常的结晶记忆效应","authors":"Jiazheng Shen, Fei Yang, Yilong Liao, Zhe Ma* and Yuesheng Li, ","doi":"10.1021/acs.macromol.4c00721","DOIUrl":null,"url":null,"abstract":"<p >A strong memory effect has been identified in copolymers even above the equilibrium melting temperature, which accelerates the subsequent recrystallization process. In this study, two series of novel 1-butene-based random copolymers were synthesized from two comonomers: 4-phenyl-1-butene (PhB) and 4-anthryl-1-butene (AnB). PhB and AnB introduced phenyl and anthryl groups, respectively, into the poly(1-butene) main chain. The occurrence and evolution of the memory effect were systematically explored in the presence of these designed counits via differential scanning calorimetry. The strong memory effect above the equilibrium melting temperature occurred in both copolymers, while their critical compositions of incorporation varied largely. The memory effect was triggered with the incorporated PhB counits up to 5.33 mol % for a fixed annealing period of 10 min. However, the incorporation of only 0.6 mol % of the sterically hindered large AnB counits induced a strong memory effect. A plot of the crystallization temperature as a function of the melt temperature (<i>T</i><sub>melt</sub>) showed a counterintuitive bell-shaped trend for AnB copolymers. The strength of the memory effect increased on extending the holding duration, contrary to the customary decaying behavior. Such a developed memory effect clearly explains the origin of the observed inversion of the crystallization rate over a broad temperature range.</p>","PeriodicalId":51,"journal":{"name":"Macromolecules","volume":null,"pages":null},"PeriodicalIF":5.1000,"publicationDate":"2024-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Unusual Memory Effect of Crystallization Raised by 4-Phenyl-1-butene and 4-Anthryl-1-butene Comonomers in 1-Butene-Based Copolymers\",\"authors\":\"Jiazheng Shen, Fei Yang, Yilong Liao, Zhe Ma* and Yuesheng Li, \",\"doi\":\"10.1021/acs.macromol.4c00721\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >A strong memory effect has been identified in copolymers even above the equilibrium melting temperature, which accelerates the subsequent recrystallization process. In this study, two series of novel 1-butene-based random copolymers were synthesized from two comonomers: 4-phenyl-1-butene (PhB) and 4-anthryl-1-butene (AnB). PhB and AnB introduced phenyl and anthryl groups, respectively, into the poly(1-butene) main chain. The occurrence and evolution of the memory effect were systematically explored in the presence of these designed counits via differential scanning calorimetry. The strong memory effect above the equilibrium melting temperature occurred in both copolymers, while their critical compositions of incorporation varied largely. The memory effect was triggered with the incorporated PhB counits up to 5.33 mol % for a fixed annealing period of 10 min. However, the incorporation of only 0.6 mol % of the sterically hindered large AnB counits induced a strong memory effect. A plot of the crystallization temperature as a function of the melt temperature (<i>T</i><sub>melt</sub>) showed a counterintuitive bell-shaped trend for AnB copolymers. The strength of the memory effect increased on extending the holding duration, contrary to the customary decaying behavior. Such a developed memory effect clearly explains the origin of the observed inversion of the crystallization rate over a broad temperature range.</p>\",\"PeriodicalId\":51,\"journal\":{\"name\":\"Macromolecules\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.1000,\"publicationDate\":\"2024-06-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Macromolecules\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.macromol.4c00721\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecules","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.macromol.4c00721","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Unusual Memory Effect of Crystallization Raised by 4-Phenyl-1-butene and 4-Anthryl-1-butene Comonomers in 1-Butene-Based Copolymers
A strong memory effect has been identified in copolymers even above the equilibrium melting temperature, which accelerates the subsequent recrystallization process. In this study, two series of novel 1-butene-based random copolymers were synthesized from two comonomers: 4-phenyl-1-butene (PhB) and 4-anthryl-1-butene (AnB). PhB and AnB introduced phenyl and anthryl groups, respectively, into the poly(1-butene) main chain. The occurrence and evolution of the memory effect were systematically explored in the presence of these designed counits via differential scanning calorimetry. The strong memory effect above the equilibrium melting temperature occurred in both copolymers, while their critical compositions of incorporation varied largely. The memory effect was triggered with the incorporated PhB counits up to 5.33 mol % for a fixed annealing period of 10 min. However, the incorporation of only 0.6 mol % of the sterically hindered large AnB counits induced a strong memory effect. A plot of the crystallization temperature as a function of the melt temperature (Tmelt) showed a counterintuitive bell-shaped trend for AnB copolymers. The strength of the memory effect increased on extending the holding duration, contrary to the customary decaying behavior. Such a developed memory effect clearly explains the origin of the observed inversion of the crystallization rate over a broad temperature range.
期刊介绍:
Macromolecules publishes original, fundamental, and impactful research on all aspects of polymer science. Topics of interest include synthesis (e.g., controlled polymerizations, polymerization catalysis, post polymerization modification, new monomer structures and polymer architectures, and polymerization mechanisms/kinetics analysis); phase behavior, thermodynamics, dynamic, and ordering/disordering phenomena (e.g., self-assembly, gelation, crystallization, solution/melt/solid-state characteristics); structure and properties (e.g., mechanical and rheological properties, surface/interfacial characteristics, electronic and transport properties); new state of the art characterization (e.g., spectroscopy, scattering, microscopy, rheology), simulation (e.g., Monte Carlo, molecular dynamics, multi-scale/coarse-grained modeling), and theoretical methods. Renewable/sustainable polymers, polymer networks, responsive polymers, electro-, magneto- and opto-active macromolecules, inorganic polymers, charge-transporting polymers (ion-containing, semiconducting, and conducting), nanostructured polymers, and polymer composites are also of interest. Typical papers published in Macromolecules showcase important and innovative concepts, experimental methods/observations, and theoretical/computational approaches that demonstrate a fundamental advance in the understanding of polymers.