Hydrogen diffusion and precipitation influenced by non-uniformly distributed stress in zirconium alloy with different textures

Hydrogen embrittlement is a crucial factor for the performance and life of zirconium alloys in nuclear industry. During service, the residual stress in the materials induces re-distribution of hydrogen, which further affects the fracture behavior. This study is dedicated to investigating the hydrogen diffusion and precipitation under the meso‑scale non-uniform deformation field. The texture effect of hydrogen behavior was examined by considering three different texture scenarios: grains with c-axis deviating from the tensile direction of random angle, 0°and 90° The cases were termed Random, T000, and T0900 respectively. The crystal plasticity finite element method (CPFEM) was employed to simulate the stress-assisted diffusion of hydrogen atoms in the polycrystalline zirconium alloy. It is determined that the T0900 case gets fewer regions with higher hydrostatic stress gradient, which helps relieve the hydrogen concentration. Compared to the T0900 texture, the interaction between soft and hard grains in the Random and T000 texture conditions results in higher stress gradient and severe hydrogen concentration. Statistical analysis was conducted and the hydrogen concentration in the three textures presents a normal distribution. T0900 gets a relatively lower overall hydrogen concentration while the T000 texture gets severe hydrogen concentration larger than 120 wt.ppm. In Random and T000 textures, hydrogen tends to accumulate at grain interior and boundaries, and continuous hydrogen concentration band forms along adjacent GBs. The T0900 scenario is free of large continuous hydrogen concentration zones, which helps reduces the adverse effects of hydrogen diffusion and precipitation. The findings of the work advance the understanding of the hydrogen behavior affected by stress heterogeneity and texture, which is the basis for the exploration of hydrogen embrittlement.