利用原位 X 射线诊断法测量重离子加热金刚石的温度和结构

IF 5.5 3区 材料科学 Q2 CHEMISTRY, PHYSICAL ACS Applied Energy Materials Pub Date : 2024-06-12 DOI:10.1063/5.0203005
J. Lütgert, P. Hesselbach, M. Schörner, V. Bagnoud, R. Belikov, P. Drechsel, B. Heuser, O. Humphries, P. Katrík, B. Lindqvist, C. Qu, R. Redmer, D. Riley, G. Schaumann, S. Schumacher, A. Tauschwitz, D. Varentsov, K. Weyrich, X. Yu, B. Zielbauer, Zs. Major, P. Neumayer, D. Kraus
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引用次数: 0

摘要

我们展示了用强脉冲重离子加热单晶金刚石样品所产生的光谱分辨 X 射线散射和 X 射线衍射的现场测量结果。通过这种方法,我们确定了样品在几微秒时间跨度内的加热动态及其微观和宏观结构的完整性。将弹性散射与非弹性散射的比率与最先进的密度泛函理论分子动力学模拟联系起来,可以推断出 1300 K 左右的平均温度,这与停止功率计算的预测结果一致。同时进行的衍射测量没有显示出任何材料体积石墨化的迹象,但确实显示出金刚石样品开始断裂。我们的实验为今后在反质子和离子研究设施(Facility for Antiproton and Ion Research)进行研究铺平了道路,该设施的重离子束强度将大幅提高。
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Temperature and structure measurements of heavy-ion-heated diamond using in situ X-ray diagnostics
We present in situ measurements of spectrally resolved X-ray scattering and X-ray diffraction from monocrystalline diamond samples heated with an intense pulse of heavy ions. In this way, we determine the samples’ heating dynamics and their microscopic and macroscopic structural integrity over a timespan of several microseconds. Connecting the ratio of elastic to inelastic scattering with state-of-the-art density functional theory molecular dynamics simulations allows the inference of average temperatures around 1300 K, in agreement with predictions from stopping power calculations. The simultaneous diffraction measurements show no hints of any volumetric graphitization of the material, but do indicate the onset of fracture in the diamond sample. Our experiments pave the way for future studies at the Facility for Antiproton and Ion Research, where a substantially increased intensity of the heavy ion beam will be available.
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来源期刊
ACS Applied Energy Materials
ACS Applied Energy Materials Materials Science-Materials Chemistry
CiteScore
10.30
自引率
6.20%
发文量
1368
期刊介绍: ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.
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