增强 K2Ti6O13/g-C3N4 异质结的模拟太阳光光催化性能

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-06-12 DOI:10.1142/s0217984924504104
Zhi Li, Yuhan Jing, Qianxu Ye, Jie Wang, Nan Sun, Liexing Zhou, Jinming Cai
{"title":"增强 K2Ti6O13/g-C3N4 异质结的模拟太阳光光催化性能","authors":"Zhi Li, Yuhan Jing, Qianxu Ye, Jie Wang, Nan Sun, Liexing Zhou, Jinming Cai","doi":"10.1142/s0217984924504104","DOIUrl":null,"url":null,"abstract":"In this study, K2Ti6O[Formula: see text] (KTO) nanowires were doped with carbon (CKTO) via a novel solid-phase approach at 800∘C for the first time using ethanol, KF, and TiO2. In addition to the lower sintering temperature, a shorter insulation period was achieved compared to the conventional solid-phase method. Furthermore, by combining and calcining CKTO and g-C3N4, a CKTO/g-C3N4 heterojunction composite was produced. The rate at which CKTO/g-C3N4 photocatalytically degraded methylene blue was higher than those of pure CKTO and g-C3N4. Our study indicates that adding g-C3N4 enhances photocatalytic performance by reducing the recombination rate of photogenerated electron–hole pairs and narrowing the bandgap of the CKTO/g-C3N4 heterostructure. This paper presents a novel method for creating KTO composites in an eco-friendly and productive manner for the photocatalytic degradation of organic colors.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":"31 33","pages":""},"PeriodicalIF":17.7000,"publicationDate":"2024-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Enhanced simulated sunlight photocatalytic performance in K2Ti6O13/g-C3N4 heterojunction\",\"authors\":\"Zhi Li, Yuhan Jing, Qianxu Ye, Jie Wang, Nan Sun, Liexing Zhou, Jinming Cai\",\"doi\":\"10.1142/s0217984924504104\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this study, K2Ti6O[Formula: see text] (KTO) nanowires were doped with carbon (CKTO) via a novel solid-phase approach at 800∘C for the first time using ethanol, KF, and TiO2. In addition to the lower sintering temperature, a shorter insulation period was achieved compared to the conventional solid-phase method. Furthermore, by combining and calcining CKTO and g-C3N4, a CKTO/g-C3N4 heterojunction composite was produced. The rate at which CKTO/g-C3N4 photocatalytically degraded methylene blue was higher than those of pure CKTO and g-C3N4. Our study indicates that adding g-C3N4 enhances photocatalytic performance by reducing the recombination rate of photogenerated electron–hole pairs and narrowing the bandgap of the CKTO/g-C3N4 heterostructure. This paper presents a novel method for creating KTO composites in an eco-friendly and productive manner for the photocatalytic degradation of organic colors.\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":\"31 33\",\"pages\":\"\"},\"PeriodicalIF\":17.7000,\"publicationDate\":\"2024-06-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://doi.org/10.1142/s0217984924504104\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.1142/s0217984924504104","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

在这项研究中,首次使用乙醇、KF 和 TiO2 在 800∘C 温度下通过新型固相方法在 K2Ti6O [式:见正文] (KTO)纳米线中掺杂了碳(CKTO)。与传统的固相方法相比,该方法不仅烧结温度更低,而且绝缘时间更短。此外,通过将 CKTO 和 g-C3N4 结合并煅烧,制备出了 CKTO/g-C3N4 异质结复合材料。与纯 CKTO 和 g-C3N4 相比,CKTO/g-C3N4 光催化降解亚甲基蓝的速率更高。我们的研究表明,添加 g-C3N4 可降低光生电子-空穴对的重组率,缩小 CKTO/g-C3N4 异质结构的带隙,从而提高光催化性能。本文提出了一种新型方法,以环保和高效的方式制造 KTO 复合材料,用于有机色素的光催化降解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Enhanced simulated sunlight photocatalytic performance in K2Ti6O13/g-C3N4 heterojunction
In this study, K2Ti6O[Formula: see text] (KTO) nanowires were doped with carbon (CKTO) via a novel solid-phase approach at 800∘C for the first time using ethanol, KF, and TiO2. In addition to the lower sintering temperature, a shorter insulation period was achieved compared to the conventional solid-phase method. Furthermore, by combining and calcining CKTO and g-C3N4, a CKTO/g-C3N4 heterojunction composite was produced. The rate at which CKTO/g-C3N4 photocatalytically degraded methylene blue was higher than those of pure CKTO and g-C3N4. Our study indicates that adding g-C3N4 enhances photocatalytic performance by reducing the recombination rate of photogenerated electron–hole pairs and narrowing the bandgap of the CKTO/g-C3N4 heterostructure. This paper presents a novel method for creating KTO composites in an eco-friendly and productive manner for the photocatalytic degradation of organic colors.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
期刊最新文献
Leveling Up Upconverting Nanoparticles with Machine Learning. Climbing and Moving the Volcano: An Active-Site-Centric Framework for Mastering Electrocatalytic Scaling Relations. Issue Publication Information Issue Editorial Masthead Mechanistic Insights into Dinitrogen Reduction to Ammonia in Light-Controlled Nanocrystal:Nitrogenase Complexes
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1