集中流。230 年的结晶议程

Askhab Askhabov
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摘要

我们简要介绍了伴随溶液中晶体生长和溶解的浓度流的发现和研究历史。我们描述了与浓度流相关的各种晶体生长后果(物质向晶体生长输送机制的变化、上下表面生长差异、晶体形状变形、晶体周围出现流体力学边界层和扩散层等)。特别分析了浓度流影响下溶液的浓度分化(分层)现象。确定了晶体生长过程中溶液分化的标准条件。
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Concentration flows. 230 years in the crystallogenic agenda
We briefly outlined the history of discovery and study of concentration flows accompanying the growth and dissolution of crystals in solutions. Various crystallogenic consequences associated with concentration flows (changes in the mechanisms of transport of matter to the growing crystal, differences in the growth of the upper and lower faces, distortion of crystal shape, occurrence of hydrodynamic boundary layer around a crystal together with the diffusion layer, etc.) were described. The phenomenon of concentration differentiation (stratification) of the solution under the influence of concentration flows was especially analyzed. The criteria conditions for differentiation of the solution during crystal growth were determined.
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