基于新型螺旋流场的钒氧化还原液流电池传质性能的数值分析与研究

Zeyu Li, Fuzhen Wang, Zebo Huang
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摘要

全钒氧化还原液流电池(VRFB)的高安全系数使其成为大规模固定储能的主要选择。然而,由于能量密度低、成本高,它们的进一步发展受到了限制。流场性能成为影响电池性能的关键因素。在本文中,我们提出了一种新型螺旋流场(NSFF),它不同于常见的蛇形流场和平行流场。我们的研究结果表明,在流速为 180 mL min-1 和电流密度为 90 mA cm-2 的条件下,NSFF 比蛇形流场和平行流场的能量效率分别高出 3.65% 和 9.8%。此外,经过多次循环后,NSFF 的健康状况达到了令人印象深刻的 72.18%,分别比蛇形流场和平行流场高出 9.97% 和 32.12%。
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Numerical Analysis and Research on Mass Transfer Performance of Vanadium Redox Flow Battery Based on Novel Spiral Flow Field
The high safety factor of all-vanadium redox flow batteries (VRFBs) has positioned them as a leading choice for large-scale stationary energy storage. However, their further development is limited by their low energy density and high cost. Flow field performance emerges as a critical factor significantly influencing battery performance. In this paper, we propose a novel spiral flow field (NSFF), which deviates from the commonly serpentine and parallel flow fields. Our research findings demonstrate that, at a flow rate of 180 mL min-1 and a current density of 90 mA cm-2, the NSFF achieves, respectively, 3.65% and 9.8% higher energy efficiency compared to the serpentine and parallel flow fields. Moreover, the state of health of the NSFF after multiple cycles reaches an impressive level of 72.18%, surpassing that of the serpentine and parallel flow fields by 9.97% and 32.12%, respectively.
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