不稳定烃类凝析油脱甲烷技术方案的优化

Anastasia I. Kazakova, Andrey V. Kurochkin, S. V. Akulov, Alena G. Chirkova, Iskander R. Sungatulin, S. R. Khafizova
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摘要

实现 C2+ 成分高回收率的现代技术工艺是低温气体精馏,包括不稳定碳氢化合物冷凝物的脱甲烷化阶段。脱甲烷基于低温精馏分离气液混合物。目标气体分离产品的产量和质量取决于脱甲烷器的操作。因此,必须合理安排脱甲烷装置的操作,以保持塔内的分离质量,并尽量减少乙烷与商品气的损失。优化工艺的方法之一是采用旨在降低供应给塔的气体流速的技术。文章分析了领先工程公司林德(Linde)的技术解决方案,并揭示了技术方案中的瓶颈:乙烷回收深度低,这与干脱气体中乙烷的高损失有关;脱甲烷器上部直径大,这与塔内气相负荷高有关。为此,"PEGAZ "研究设计院开发了优化的工艺技术。LLC 公司开发的优化工艺技术。结果表明,在将气液流送入脱甲烷器之前对其进行三级分离会产生意想不到的结果:防止可能的乙烷夹带、减少乙烷损失、减少脱甲烷器上部的气相负荷,因为只有分离残渣作为进料流送入塔中。采用这种改良方案可以提高乙烷回收率,减少乙烷损失,降低塔的质量和尺寸特性及其成本。
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OPTIMIZATION OF TECHNOLOGICAL SCHEME FOR UNSTABLE HYDROCARBON CONDENSATES DEMETHANIZATION
The modern technological process allowing to achieve high recovery of C2+ components is low-temperature gas rectification, including demethanization stage of unstable hydrocarbon condensates. Demethanization is based on separation of gas-liquid mixture by low-temperature rectification. The yield and quality of the target gas separation products depend on the demethanizer operation. In this connection it is important to arrange the demethanization unit operation so as to preserve the separation quality in the column and minimize ethane losses with commercial gas. One of the methods of process optimization is the use of technological techniques aimed at reducing the flow rate of gas supplied to the column.This article presents a brief overview of the demethanization process, considers the features of demethanizer operation. Technological solutions of the leading engineering company Linde are analyzed and bottlenecks in the technological scheme are revealed: low depth of ethane recovery, which is associated with high losses of ethane with dry stripped gas; large diameter of the upper part of the demethanizer, which is associated with high loads of the column on the vapor phase. In this connection the optimized technology of the process developed by Research and Design Institute «PEGAZ» LLC is offered. It is shown that application of three-stage separation of gas-liquid streams before their feeding into the demethanizer leads to unexpected results: prevention of possible ethane entrainment, reducing ethane losses, reduction of vapor phase load in the upper part of the demethanizer due to feeding only separation residues into the column as a feed stream. Implementation of such a modified scheme allows increasing the degree of ethane recovery, reducing ethane losses, reducing the mass and dimensional characteristics of the column and its cost.
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