汽车燃料中各碳氢化合物的二氧化碳具体排放量

Marat M. Yakupov, Radmir R. Aznabaev, Ekaterina V. Simonova, Farhaд Sh. Vildanov, Irek M. Gubaydullin, Marat N. Rakhimov
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摘要

大气中温室气体的增加被认为是我们这个时代的全球性问题之一,因为这种现象会导致环境温度升高。国际社会试图采取各种措施减少温室气体排放。在《联合国气候变化框架公约》框架内,2015 年通过了《巴黎协定》,旨在减少温室气体排放,限制全球气温上升。2016 年,俄罗斯加入了《巴黎气候协定》,并承诺到 2030 年将温室气体排放量从 1990 年的水平减少 25%-30%。在中期内,交通是并将继续是二氧化碳的主要排放者之一。任何燃料燃烧产生的二氧化碳排放量主要取决于其化学成分。现代汽车燃料的成分包括石蜡、环烷、烯烃和芳香烃,有时还会在其成分中加入含氧化合物。文章首次介绍了根据分子中碳原子数对汽车燃料中各类碳氢化合物的二氧化碳具体排放量进行研究的结果。研究结果表明,车用燃料成分中所含碳氢化合物的二氧化碳具体排放量在组别组成和组别内部都存在很大差异。例如,丁烷和甲苯等车用汽油中的高辛烷值成分的二氧化碳具体排放量相差 10.6%,而按释放的能量单位计算,则相差 24% 以上。
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SPECIFIC CARBON DIOXIDE EMISSIONS OF INDIVIDUAL HYDROCARBONS IN MOTOR FUELS
The increase in greenhouse gases in the atmosphere is considered to be one of the global problems of our time, as this phenomenon leads to an increase in ambient temperature. The international community tries to take various measures to reduce greenhouse gas emissions. Within the framework of the UN Framework Convention on Climate Change, the Paris Agreement was adopted in 2015, aimed at reducing greenhouse gas emissions and limiting global temperature increases. In 2016 Russia joined the Paris Agreement on Climate and committed to reduce greenhouse gas emissions by 25–30 % since 1990 levels by 2030. Transport is and will remain one of the main emitters of carbon dioxide emissions in the medium term. CO2 emissions from the combustion of any fuel depend primarily on its chemical composition. The composition of modern motor fuels includes paraffin, naphthenic, olefin and aromatic hydrocarbons, and sometimes oxygen-containing compounds are introduced into their composition. The article presents for the first time the results of studies of specific CO2 emissions of various classes of hydrocarbons included in motor fuels, depending on the number of carbon atoms in the molecule. It is shown that the specific CO2 emissions of hydrocarbons included in the composition of motor fuels differ greatly both in group composition and within groups themselves. Specific CO2 emissions of such high-octane components of automobile gasoline as butanes and toluene, for example, differ by 10.6 %, and in terms of unit of energy released – by more than 24 %.
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