V. O. Zazhigalov, O. V. Sachuk, O. V. Kiziun, O. A. Diyuk, I. V. Bacherikova
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Mechanochemical and Sonochemical Obtaining of Nanosized Oxides Materials and Catalysts: A Review
The promising application of mechanochemical (MC) and sonochemical (SC) synthesis methods for the obtaining of nano-dispersed oxide materials with a perovskite structure (BaTiO3, CaTiO3, and LiNbO3) and higher specific surface value as compared to samples obtained by traditional methods is shown. Synthesized samples exhibit high photocatalytic activity in the oxidative degradation of metronidazole and chloramphenicol drugs, as well as a promethrin herbicide in an aqueous medium exceeding known analogs. The possibilities of MC and SC in the synthesis of zinc and bismuth molybdates with the obtaining of their nanostructures with different morphologies, in particular bars, needles, rods, and spheres, are shown. It is established that prepared samples demonstrate high activity in the processes of ethanol oxidation to acetaldehyde (β-ZnMoO4) or acetic acid (α-ZnMoO4), oxidative dehydrogenation of hydrocarbons of the industrial fraction of oil processing with the obtaining of 1,3-butadiene (Bi2Mo3O12).
期刊介绍：
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.
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