分子内锁促进平面三环融合高能化合物的形成

IF 4.9 1区 化学 Q1 CHEMISTRY, ORGANIC Organic Letters Pub Date : 2024-06-20 DOI:10.1021/acs.orglett.4c01783
Yubing Liu, Xun Zhang, Jie Li, Ao Kou, Hongxin Ding, Siping Pang* and Chunlin He*, 
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引用次数: 0

摘要

通过简单高效的方法开发新型融合环框架为研制先进的炸药提供了蓝图。本研究通过 C-NH2 定向环化反应的分子内环化策略合成了六种新的 [5,6,5]- 三环融合高能化合物(I-VI)。这项工作不仅推动了融合环状高能化合物的发展,而且突出了它们作为二次或耐热炸药的潜在应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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An Intramolecular-Lock Facilitates Planar Tricyclic Fused Energetic Compounds

Exploiting novel fused cyclic frameworks through simple and efficient methods has provided a blueprint for developing advanced explosives. In this study, six new [5,6,5]-tricyclic fused energetic compounds (IVI) were synthesized through an intramolecular cyclization strategy involving a C-NH2 directed cyclization reaction. The work not only boosts the development of fused cyclic energetic compounds but also highlights their potential applications as secondary or heat-resistant explosives.

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来源期刊
Organic Letters
Organic Letters 化学-有机化学
CiteScore
9.30
自引率
11.50%
发文量
1607
审稿时长
1.5 months
期刊介绍: Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.
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