Lian Zhou, Yanfeng Cui, Han Zhao, QingHong Zhang, Qingchen Fan, Xiaomin He, Qi Wu* and Jun Zhang*,
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引用次数: 0
摘要
这项研究利用双配位体成功构建了三种配位聚合物,并通过单晶 X 射线衍射对其进行了表征。这些化合物在配位键方向的中心空间群和中心空间群中结晶,具有一维链接结构和二维层状结构,金属原子的配位几何结构也各不相同。所有化合物都表现出良好的热稳定性和发光特性,其中化合物 2 表现出良好的二次谐波发生(SHG)响应。这项研究采用的方法为利用双配位体和变化的金属盐来获得具有特定性能的配位材料微结构提供了一种可行的方法。
Preparing Coordination Polymers with Acentric–Centric Structural Arrangements Related to SHG Response
Three coordination polymers were successfully constructed in this work by applying biligands and were distinctly characterized through single crystal X-ray diffraction. The compounds crystallized in acentric and centric space groups under the direction of coordination bonds and adopted 1-dimensional link and 2-dimensional layer structures, as well as different coordination geometries for metal atoms. All compounds exhibited good thermal stability and luminescence properties, and compound 2 exhibited a good second harmonic generation (SHG) response. The method used in this work offers a feasible approach to using biligand and changing metal salt to obtain the microstructures of coordination materials with specific properties.
期刊介绍:
Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.