{"title":"镍替代和诱导孔隙率的协同效应:提高钴酸盐在碱性介质中对 OER 和 MOR 的电催化性能","authors":"Prakhar Mishra, Reena Parihar, Yamini Singh, Narendra Kumar Singh","doi":"10.1016/j.jallcom.2024.175375","DOIUrl":null,"url":null,"abstract":"The quest for sustainable and efficient energy conversion technologies has intensified research into advanced materials for electrochemical reactions, such as the oxygen evolution reaction (OER) and methanol oxidation reaction (MOR). Transition metal oxides have emerged as promising catalysts due to their abundance, low cost, and adjustable electronic properties. Among these, Nickel (Ni)-based compounds are particularly noteworthy for their catalytic activity and stability. This research paper explores the crucial impact of Nickel (Ni) substitution and introducing porosity on the valence states of metal ions and their mass transport in the context of OER and MOR. In this study, we present a step-by-step surfactant (Brij 58) assisted synthesis approach for the preparation of mesoporous CoO and NiCoO. The synthesised material has been physiochemically characterised by Fourier transform Infrared Spectroscopy (FTIR), Scanning electron microscopic/Energy-dispersive X-ray spectroscopy (SEM/EDS) and High-resolution transmission electron microscopy (HR-TEM), X-ray diffraction (XRD), and inductively coupled plasma mass spectrometry (ICP-MS) analyses. Additionally, the impact of these alterations on electrocatalytic activity, reaction kinetics, and electrochemical stability during OER/MOR has been explored by Cyclic Voltammetry (CV), Linear Sweep Voltammetry (LSV), Tafel, Electrochemical Impedance Spectroscopy (EIS) and chronoamperometric experiments. Mesoporous NiCoO exhibits exceptional electrocatalytic performance with current densities of 46.8 mA/cm for OER and 214.5 mA/cm for MOR at 550 mV. By shedding light on the intricate interplay between metal substitution, porosity, and valence states, this research aims to provide valuable insights for the evolution of enhanced cobaltite electrocatalysts for sustainable water splitting and MOR.","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":null,"pages":null},"PeriodicalIF":5.8000,"publicationDate":"2024-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synergetic effect of Ni substitution and induced porosity: Enhancing the electrocatalytic performance of cobaltite towards OER and MOR in alkaline medium\",\"authors\":\"Prakhar Mishra, Reena Parihar, Yamini Singh, Narendra Kumar Singh\",\"doi\":\"10.1016/j.jallcom.2024.175375\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The quest for sustainable and efficient energy conversion technologies has intensified research into advanced materials for electrochemical reactions, such as the oxygen evolution reaction (OER) and methanol oxidation reaction (MOR). 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Additionally, the impact of these alterations on electrocatalytic activity, reaction kinetics, and electrochemical stability during OER/MOR has been explored by Cyclic Voltammetry (CV), Linear Sweep Voltammetry (LSV), Tafel, Electrochemical Impedance Spectroscopy (EIS) and chronoamperometric experiments. Mesoporous NiCoO exhibits exceptional electrocatalytic performance with current densities of 46.8 mA/cm for OER and 214.5 mA/cm for MOR at 550 mV. 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引用次数: 0
摘要
对可持续高效能源转换技术的追求,加强了对用于电化学反应(如氧进化反应和甲醇氧化反应)的先进材料的研究。过渡金属氧化物因其丰富、低成本和可调节的电子特性而成为前景广阔的催化剂。其中,镍(Ni)基化合物的催化活性和稳定性尤为突出。本研究论文以 OER 和 MOR 为背景,探讨了镍(Ni)替代和引入孔隙率对金属离子价态及其质量传输的重要影响。在本研究中,我们介绍了一种逐步合成介孔 CoO 和 NiCoO 的表面活性剂(Brij 58)辅助方法。通过傅立叶变换红外光谱 (FTIR)、扫描电子显微镜/能量色散 X 射线光谱 (SEM/EDS) 和高分辨率透射电子显微镜 (HR-TEM)、X 射线衍射 (XRD) 以及电感耦合等离子体质谱 (ICP-MS) 分析,对合成材料进行了物理化学表征。此外,还通过循环伏安法 (CV)、线性扫描伏安法 (LSV)、塔菲尔法 (Tafel)、电化学阻抗谱法 (EIS) 和计时电流计实验探讨了这些变化对 OER/MOR 过程中的电催化活性、反应动力学和电化学稳定性的影响。介孔钴酸镍表现出卓越的电催化性能,在 550 mV 电压下,OER 和 MOR 的电流密度分别为 46.8 mA/cm 和 214.5 mA/cm。通过阐明金属替代、孔隙率和价态之间错综复杂的相互作用,本研究旨在为可持续水分离和 MOR 的增强型钴酸盐电催化剂的发展提供有价值的见解。
Synergetic effect of Ni substitution and induced porosity: Enhancing the electrocatalytic performance of cobaltite towards OER and MOR in alkaline medium
The quest for sustainable and efficient energy conversion technologies has intensified research into advanced materials for electrochemical reactions, such as the oxygen evolution reaction (OER) and methanol oxidation reaction (MOR). Transition metal oxides have emerged as promising catalysts due to their abundance, low cost, and adjustable electronic properties. Among these, Nickel (Ni)-based compounds are particularly noteworthy for their catalytic activity and stability. This research paper explores the crucial impact of Nickel (Ni) substitution and introducing porosity on the valence states of metal ions and their mass transport in the context of OER and MOR. In this study, we present a step-by-step surfactant (Brij 58) assisted synthesis approach for the preparation of mesoporous CoO and NiCoO. The synthesised material has been physiochemically characterised by Fourier transform Infrared Spectroscopy (FTIR), Scanning electron microscopic/Energy-dispersive X-ray spectroscopy (SEM/EDS) and High-resolution transmission electron microscopy (HR-TEM), X-ray diffraction (XRD), and inductively coupled plasma mass spectrometry (ICP-MS) analyses. Additionally, the impact of these alterations on electrocatalytic activity, reaction kinetics, and electrochemical stability during OER/MOR has been explored by Cyclic Voltammetry (CV), Linear Sweep Voltammetry (LSV), Tafel, Electrochemical Impedance Spectroscopy (EIS) and chronoamperometric experiments. Mesoporous NiCoO exhibits exceptional electrocatalytic performance with current densities of 46.8 mA/cm for OER and 214.5 mA/cm for MOR at 550 mV. By shedding light on the intricate interplay between metal substitution, porosity, and valence states, this research aims to provide valuable insights for the evolution of enhanced cobaltite electrocatalysts for sustainable water splitting and MOR.
期刊介绍:
The Journal of Alloys and Compounds is intended to serve as an international medium for the publication of work on solid materials comprising compounds as well as alloys. Its great strength lies in the diversity of discipline which it encompasses, drawing together results from materials science, solid-state chemistry and physics.