在 700 纳米到 1750 纳米的近红外光谱范围内对钬的原子和离子光谱进行谱线鉴定

IF 3.2 2区 化学 Q1 SPECTROSCOPY Spectrochimica Acta Part B: Atomic Spectroscopy Pub Date : 2024-07-01 DOI:10.1016/j.sab.2024.106950
Muammer Zengin , Seda Kın Barka , İpek K. Öztürk , Ilze Klincare , Sophie Kröger , Gönül Başar
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引用次数: 0

摘要

这项研究的目的是将原子钬(Ho)和单电离钬(Ho)的光谱线扩展到 1750 纳米以下的近红外波长范围。使用傅立叶变换光谱仪测量了以氖气或氩气为缓冲气体的钬空心阴极放电灯在不同光谱范围内的光谱。光谱范围从 700 纳米到 1750 纳米,即从 5710cm-1 到 14280cm-1。共检测到近 800 条光谱线。根据原子和离子 Ho 的已知能级,589 条谱线可归类为 Ho I 变换,31 条谱线可归类为 Ho II 变换。其余的 171 条谱线大多可根据使用不同缓冲气体测量的光谱中不同的信噪比归类为不同的 Ho I 或 Ho II。在 1200 nm 到 1750 nm 的波长范围内,首次提出了一个 Ho 线列表。在 700 纳米到 1200 纳米的波长范围内,216 条线迄今为止尚未在文献中列出。
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Line identification of atomic and ionic spectra of Holmium in the near infrared spectral range from 700 nm to 1750 nm

The aim of the study is to extend the list of spectral lines of atomic and single ionized holmium (Ho) into the near infrared wavelength range up to 1750 nm. Spectra of a Ho hollow cathode discharge lamp with neon or argon as buffer gases have been measured with a Fourier Transform spectrometer in different spectral ranges. In total, the range from 700 nm to 1750 nm i.e. from 5710cm1 to 14280cm1 has been covered. A total of almost 800 spectral lines were detected. Based on the known energy levels of atom and ion Ho, 589 lines could be classified as Ho I transitions and 31 lines as Ho II transitions. The remaining 171 lines could mostly be classified as different Ho I or Ho II, based on different signal-to-noise ratios in spectra measured with different buffer gases. In the wavelength range from 1200 nm to 1750 nm, a list of Ho lines is presented for the first time. In the wavelength range from 700 nm to 1200 nm 216 lines had not been listed in literature up to now.

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来源期刊
CiteScore
6.10
自引率
12.10%
发文量
173
审稿时长
81 days
期刊介绍: Spectrochimica Acta Part B: Atomic Spectroscopy, is intended for the rapid publication of both original work and reviews in the following fields: Atomic Emission (AES), Atomic Absorption (AAS) and Atomic Fluorescence (AFS) spectroscopy; Mass Spectrometry (MS) for inorganic analysis covering Spark Source (SS-MS), Inductively Coupled Plasma (ICP-MS), Glow Discharge (GD-MS), and Secondary Ion Mass Spectrometry (SIMS). Laser induced atomic spectroscopy for inorganic analysis, including non-linear optical laser spectroscopy, covering Laser Enhanced Ionization (LEI), Laser Induced Fluorescence (LIF), Resonance Ionization Spectroscopy (RIS) and Resonance Ionization Mass Spectrometry (RIMS); Laser Induced Breakdown Spectroscopy (LIBS); Cavity Ringdown Spectroscopy (CRDS), Laser Ablation Inductively Coupled Plasma Atomic Emission Spectroscopy (LA-ICP-AES) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS). X-ray spectrometry, X-ray Optics and Microanalysis, including X-ray fluorescence spectrometry (XRF) and related techniques, in particular Total-reflection X-ray Fluorescence Spectrometry (TXRF), and Synchrotron Radiation-excited Total reflection XRF (SR-TXRF). Manuscripts dealing with (i) fundamentals, (ii) methodology development, (iii)instrumentation, and (iv) applications, can be submitted for publication.
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