{"title":"亚氨基-λ3-碘烷催化的 N-三烯丙基醛亚胺的合成","authors":"Shun Sunagawa , Yoko Tezuka , Akira Tsubouchi , Akira Yoshimura , Akio Saito","doi":"10.1039/d4qo00875h","DOIUrl":null,"url":null,"abstract":"<div><div>We report a catalytic synthesis of <em>N</em>-triflyl aldimines from aldehydes and triflylamide using imino-λ<sup>3</sup>-iodane generated <em>in situ</em> from an iodosylarene precatalyst and triflylamide. In the present reaction, imino-λ<sup>3</sup>-iodane works as an acid–base cooperative catalyst to activate aldehydes and triflylamide.</div></div>","PeriodicalId":94379,"journal":{"name":"Organic chemistry frontiers : an international journal of organic chemistry","volume":"11 17","pages":"Pages 4716-4721"},"PeriodicalIF":0.0000,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of N-triflyl aldimines catalyzed by imino-λ3-iodane†\",\"authors\":\"Shun Sunagawa , Yoko Tezuka , Akira Tsubouchi , Akira Yoshimura , Akio Saito\",\"doi\":\"10.1039/d4qo00875h\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>We report a catalytic synthesis of <em>N</em>-triflyl aldimines from aldehydes and triflylamide using imino-λ<sup>3</sup>-iodane generated <em>in situ</em> from an iodosylarene precatalyst and triflylamide. In the present reaction, imino-λ<sup>3</sup>-iodane works as an acid–base cooperative catalyst to activate aldehydes and triflylamide.</div></div>\",\"PeriodicalId\":94379,\"journal\":{\"name\":\"Organic chemistry frontiers : an international journal of organic chemistry\",\"volume\":\"11 17\",\"pages\":\"Pages 4716-4721\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-07-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Organic chemistry frontiers : an international journal of organic chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2052412924004686\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/7/1 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic chemistry frontiers : an international journal of organic chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2052412924004686","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/7/1 0:00:00","PubModel":"Epub","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis of N-triflyl aldimines catalyzed by imino-λ3-iodane†
We report a catalytic synthesis of N-triflyl aldimines from aldehydes and triflylamide using imino-λ3-iodane generated in situ from an iodosylarene precatalyst and triflylamide. In the present reaction, imino-λ3-iodane works as an acid–base cooperative catalyst to activate aldehydes and triflylamide.
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