{"title":"亚氨基-λ3-碘烷催化的 N-三烯丙基醛亚胺的合成","authors":"Shun Sunagawa, Yoko Tezuka, Akira Tsubouchi, Akira Yoshimura, Akio Saito","doi":"10.1039/d4qo00875h","DOIUrl":null,"url":null,"abstract":"We report a catalytic synthesis of <em>N</em>-triflyl aldimines from aldehydes and triflylamide using imino-<em>λ</em><small><sup>3</sup></small>-iodane generated in situ from iodosylarene precatalyst and triflylamide. In the present reaction, imino-<em>λ</em><small><sup>3</sup></small>-iodane works as acid-base cooperative catalyst to activate aldehydes and triflylamide.","PeriodicalId":97,"journal":{"name":"Organic Chemistry Frontiers","volume":null,"pages":null},"PeriodicalIF":4.6000,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of N-triflyl aldimines catalyzed by imino-λ3-iodane\",\"authors\":\"Shun Sunagawa, Yoko Tezuka, Akira Tsubouchi, Akira Yoshimura, Akio Saito\",\"doi\":\"10.1039/d4qo00875h\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"We report a catalytic synthesis of <em>N</em>-triflyl aldimines from aldehydes and triflylamide using imino-<em>λ</em><small><sup>3</sup></small>-iodane generated in situ from iodosylarene precatalyst and triflylamide. In the present reaction, imino-<em>λ</em><small><sup>3</sup></small>-iodane works as acid-base cooperative catalyst to activate aldehydes and triflylamide.\",\"PeriodicalId\":97,\"journal\":{\"name\":\"Organic Chemistry Frontiers\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.6000,\"publicationDate\":\"2024-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Organic Chemistry Frontiers\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d4qo00875h\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic Chemistry Frontiers","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4qo00875h","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Synthesis of N-triflyl aldimines catalyzed by imino-λ3-iodane
We report a catalytic synthesis of N-triflyl aldimines from aldehydes and triflylamide using imino-λ3-iodane generated in situ from iodosylarene precatalyst and triflylamide. In the present reaction, imino-λ3-iodane works as acid-base cooperative catalyst to activate aldehydes and triflylamide.
期刊介绍：
Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.
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