{"title":"碳纳米管中封装的 Co/Cu 纳米粒子促进了长寿命柔性可充电锌-空气电池的氧还原性能†。","authors":"Nianhao Hong, Xiaochao Liu, Xiaoxiao Li, Siyuan Peng, Chao Liu, Huan Li, Jinming Zeng, Tongxiang Liang and Xiaopeng Qi","doi":"10.1039/D3NJ05928F","DOIUrl":null,"url":null,"abstract":"<p >Rechargeable zinc–air batteries have been extensively studied as a potential solution for overcoming the challenges of energy crises and achieving sustainable development. The primary bottleneck of zinc–air batteries is the lack of efficient and low-cost dual-functional catalysts. In this study, we successfully prepared carbon nanotube-encapsulated bimetallic Co/Cu (Co/Cu<small><sub>0.2</sub></small>@NC) catalysts that exhibit excellent ORR (<em>E</em><small><sub>1/2</sub></small> = 0.838 V) and OER (overpotential of 322 mV at 10 mA cm<small><sup>−2</sup></small>) performances, exceeding those of the commercial RuO<small><sub>2</sub></small> and Pt/C catalysts. Furthermore, rechargeable liquid zinc–air batteries prepared using the Co/Cu<small><sub>0.2</sub></small>@NC catalysts show a high power density (171.44 mW cm<small><sup>−2</sup></small>), a high open circuit voltage (1.485 V), and a long life with stability for 2400 cycles (or 400 h). More importantly, flexible zinc–air batteries prepared using this catalyst exhibit a peak power density of 70.8 mW cm<small><sup>−2</sup></small> and a superior stability for 480 cycles (or 80 h). This excellent dual-functional catalyst has great potential for zinc–air battery and other energy storage applications.</p>","PeriodicalId":95,"journal":{"name":"New Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Promoted oxygen reduction performance enabled by Co/Cu nanoparticles encapsulated in carbon nanotubes for long-life flexible and rechargeable Zn–air batteries†\",\"authors\":\"Nianhao Hong, Xiaochao Liu, Xiaoxiao Li, Siyuan Peng, Chao Liu, Huan Li, Jinming Zeng, Tongxiang Liang and Xiaopeng Qi\",\"doi\":\"10.1039/D3NJ05928F\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Rechargeable zinc–air batteries have been extensively studied as a potential solution for overcoming the challenges of energy crises and achieving sustainable development. The primary bottleneck of zinc–air batteries is the lack of efficient and low-cost dual-functional catalysts. In this study, we successfully prepared carbon nanotube-encapsulated bimetallic Co/Cu (Co/Cu<small><sub>0.2</sub></small>@NC) catalysts that exhibit excellent ORR (<em>E</em><small><sub>1/2</sub></small> = 0.838 V) and OER (overpotential of 322 mV at 10 mA cm<small><sup>−2</sup></small>) performances, exceeding those of the commercial RuO<small><sub>2</sub></small> and Pt/C catalysts. Furthermore, rechargeable liquid zinc–air batteries prepared using the Co/Cu<small><sub>0.2</sub></small>@NC catalysts show a high power density (171.44 mW cm<small><sup>−2</sup></small>), a high open circuit voltage (1.485 V), and a long life with stability for 2400 cycles (or 400 h). More importantly, flexible zinc–air batteries prepared using this catalyst exhibit a peak power density of 70.8 mW cm<small><sup>−2</sup></small> and a superior stability for 480 cycles (or 80 h). This excellent dual-functional catalyst has great potential for zinc–air battery and other energy storage applications.</p>\",\"PeriodicalId\":95,\"journal\":{\"name\":\"New Journal of Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-06-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"New Journal of Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/nj/d3nj05928f\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"New Journal of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/nj/d3nj05928f","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Promoted oxygen reduction performance enabled by Co/Cu nanoparticles encapsulated in carbon nanotubes for long-life flexible and rechargeable Zn–air batteries†
Rechargeable zinc–air batteries have been extensively studied as a potential solution for overcoming the challenges of energy crises and achieving sustainable development. The primary bottleneck of zinc–air batteries is the lack of efficient and low-cost dual-functional catalysts. In this study, we successfully prepared carbon nanotube-encapsulated bimetallic Co/Cu (Co/Cu0.2@NC) catalysts that exhibit excellent ORR (E1/2 = 0.838 V) and OER (overpotential of 322 mV at 10 mA cm−2) performances, exceeding those of the commercial RuO2 and Pt/C catalysts. Furthermore, rechargeable liquid zinc–air batteries prepared using the Co/Cu0.2@NC catalysts show a high power density (171.44 mW cm−2), a high open circuit voltage (1.485 V), and a long life with stability for 2400 cycles (or 400 h). More importantly, flexible zinc–air batteries prepared using this catalyst exhibit a peak power density of 70.8 mW cm−2 and a superior stability for 480 cycles (or 80 h). This excellent dual-functional catalyst has great potential for zinc–air battery and other energy storage applications.