通过动态硫化和界面共混制造的增韧聚(3-羟基丁酸-3-羟基戊酸)/环氧天然橡胶混合物

IF 4.7 3区 工程技术 Q2 ENGINEERING, ENVIRONMENTAL Journal of Polymers and the Environment Pub Date : 2024-06-20 DOI:10.1007/s10924-024-03283-9
Napat Tomano, Tim A. Osswald, Pranut Potiyaraj, Orathai Boondamnoen, Chuanchom Aumnate
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引用次数: 0

摘要

可生物降解聚合物,尤其是聚羟基烷酸酯(PHA)及其衍生物,因其生物来源、生物相容性和令人印象深刻的生物降解性能等独特优势,在各行各业受到越来越多的关注。聚(3-羟基丁酸-3-羟基戊酸)(PHBV)是 PHAs 中最具吸引力的成员之一,具有取代传统非生物降解聚合物的巨大潜力。然而,限制 PHBV 使用的一个关键缺点是它的热不稳定性,这可能会导致加工窗口狭窄,尤其是对于注塑成型等传统熔融加工方法而言。此外,PHBV 的结晶度高、成核速度慢,因此脆性大,机械性能差。本研究通过熔融混合工艺在 PHBV 中加入环氧化天然橡胶(ENR-25 和 ENR-50),以增强 PHBV 的韧性和柔韧性。加入 5wt% 的聚丁二烯接枝马来酸酐(PB-g-MA)作为相容剂可显著提高机械性能。此外,该研究还引入了热塑性硫化弹性体(TPV)的概念,通过使用动态硫化(DV)进行熔融共混来提高机械性能,特别是 70/30 PHBV/ENR 共混物的韧性。ENRv-25和ENRv-50混合物的韧性值分别为63.0 ± 14.8 J m-1和24.4 ± 2.8 J m-1。这些发现有望推动生物可降解聚合物共混体系的设计和开发,重点是提高加工性能和机械性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Toughened Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)/Epoxidized Natural Rubber Blends Fabricated by Dynamic Vulcanization and Interfacial Compatibilization

Biodegradable polymers, particularly Polyhydroxyalkanoates (PHAs) and their derivatives, have garnered increasing attention across diverse industries owing to their distinct advantages such as bio-based sourcing, biocompatibility, and impressive biodegradability performance. Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) is one of the most attractive members of PHAs with a great potential to replace conventional non-biodegradable polymers. However, one critical drawback restricting PHBV usage is its thermal instability, which could bring about a narrow processing window, especially for conventional melt processing methods such as injection molding. Moreover, the high crystallinity and slow nucleation rate make PHBV brittle, leading to poor mechanical performance. This study incorporated epoxidized natural rubbers (ENR-25 and ENR-50) into PHBV through a melt blending process to enhance PHBV toughness and flexibility. Incorporation of 5wt% polybutadiene grafted maleic anhydride (PB-g-MA) as a compatibilizer notably enhances mechanical properties. Furthermore, the study introduces the concept of thermoplastic vulcanizate (TPV) through melt blending using dynamic vulcanization (DV) to enhance mechanical properties, particularly the toughness of the 70/30 PHBV/ENR blends, identified as the optimal blending ratio based on prior research. The resulting blend vulcanizate (PHBV/ENRv) exhibits toughness values of 63.0 ± 14.8 J m− 1 and 24.4 ± 2.8 J m− 1 for blends with ENRv-25 and ENRv-50, respectively. These findings hold promise for advancing the design and development of biodegradable polymer blend systems, with a focus on enhancing processability and mechanical performance.

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来源期刊
Journal of Polymers and the Environment
Journal of Polymers and the Environment 工程技术-高分子科学
CiteScore
9.50
自引率
7.50%
发文量
297
审稿时长
9 months
期刊介绍: The Journal of Polymers and the Environment fills the need for an international forum in this diverse and rapidly expanding field. The journal serves a crucial role for the publication of information from a wide range of disciplines and is a central outlet for the publication of high-quality peer-reviewed original papers, review articles and short communications. The journal is intentionally interdisciplinary in regard to contributions and covers the following subjects - polymers, environmentally degradable polymers, and degradation pathways: biological, photochemical, oxidative and hydrolytic; new environmental materials: derived by chemical and biosynthetic routes; environmental blends and composites; developments in processing and reactive processing of environmental polymers; characterization of environmental materials: mechanical, physical, thermal, rheological, morphological, and others; recyclable polymers and plastics recycling environmental testing: in-laboratory simulations, outdoor exposures, and standardization of methodologies; environmental fate: end products and intermediates of biodegradation; microbiology and enzymology of polymer biodegradation; solid-waste management and public legislation specific to environmental polymers; and other related topics.
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