含有有机荧光染料的光固化丙烯酸聚合物基质的发光特性

IF 1.6 4区 化学 Q4 POLYMER SCIENCE Polymer Science, Series C Pub Date : 2024-07-03 DOI:10.1134/S1811238224600071
I. A. Matveeva, V. T. Shashkova, A. V. Lyubimov, G. V. Lyubimova, L. S. Kol’tsova, A. I. Shienok, N. L. Zaichenko
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摘要

摘要 在光固化法获得的十七种聚合物基质中研究了一种有机二元化合物的发光特性,该二元化合物在其分子中结合了两种不同的发光体,即羟基取代的 2,4,5 三芳基咪唑和 8-氮甲基-7-羟基香豆素,这些聚合物基质由羟基数量不同的线性聚(甲基)丙烯酸酯和交联低聚物块性质不同的丙烯酸网络聚合物组成。材料的发光特性与激发光的波长、聚合物中羟基的存在和数量、聚氨酯基团、醚键和芳香族分子(单独或组合)的存在以及基体的柔韧性和条件极性有关。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Luminescent Properties of Photocured Acrylic Polymer Matrices Containing an Organic Fluorescent Dyad

The luminescent properties of an organic dyad that combines two different luminophores, hydroxy-substituted 2,4,5-triarylimidazole and 8-azomethine-7-hydroxycoumarin, in its molecule have been studied in seventeen polymer matrices obtained by photocuring, which are represented by linear poly(meth)acrylates differing in the amount of hydroxyl groups and acrylic network polymers differing in the nature of crosslinking oligomeric blocks. The dependence of the luminescent properties of materials on the wavelength of excitation light, as well as on the presence and amount of hydroxyl groups in polymers; the presence of urethane groups, ether bonds, and aromatic moieties (individually or in combination); and flexibility and conditional polarity of the matrix, has been established.

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来源期刊
Polymer Science, Series C
Polymer Science, Series C 工程技术-高分子科学
CiteScore
3.00
自引率
4.50%
发文量
21
审稿时长
>12 weeks
期刊介绍: Polymer Science, Series C (Selected Topics) is a journal published in collaboration with the Russian Academy of Sciences. Series C (Selected Topics) includes experimental and theoretical papers and reviews on the selected actual topics of macromolecular science chosen by the editorial board (1 issue a year). Submission is possible by invitation only. All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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