在乙二醇存在的情况下阳极氧化航空 7075-T6 铝的表面研究

IF 0.6 4区 化学 Q4 CHEMISTRY, APPLIED Russian Journal of Applied Chemistry Pub Date : 2024-06-28 DOI:10.1134/s1070427224020058
Hamid Reza Pouretedal, Hossian Rasooli, Saeed Mahbob
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引用次数: 0

摘要

摘要 研究了乙二醇(EG)、二甘醇(DEG)和三甘醇(TEG)等乙二醇衍生物在 20% w/w 硫酸、电流密度 4 A/dm2 和时间 50 分钟条件下对阳极氧化 7075-T6 铝的 Al2O3 涂层表征的影响。通过 X 射线衍射图样、扫描电子显微镜和能量色散 X 射线光谱对 Al2O3 涂层的厚度和硬度进行了测量和表征。利用线性极化法的塔夫勒图和电化学阻抗谱技术研究了 Al2O3 层的抗腐蚀性。结果表明,在乙二醇(10% w/w)的存在下,Al2O3 膜的厚度、硬度和抗腐蚀性分别增加了 30%、42% 和 40%。TEG、DEG 和 EG 的介电常数 (ε)与动态粘度 (η)之比分别为 0.48、0.89 和 2.28,这是因为在 EG > DEG > TEG 等乙二醇衍生物存在的情况下,阳极氧化铝得到了改善。
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Surface Investigation of Aerospace 7075-T6 Aluminum Anodized in the Presence of Glycols

Abstract

The effect of glycol derivatives including ethylene glycol (EG), diethylene glycol (DEG), and triethylene glycol (TEG) has been investigated on the characterization Al2O3 coating of anodized 7075-T6 aluminum in 20% w/w sulfuric acid, current density 4 A/dm2, and time 50 min. The thickness and hardness of Al2O3 layer measured and characterized by X-ray diffraction patterns, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. The Tafle plots of linear polarization method and electrochemical impedance spectroscopy technique used to investigate the resistance to corrosion Al2O3 layer. The results showed that the thickness, hardness, and resistance to corrosion of Al2O3 film are increased, respectively, 30, 42, and 40% in the presence of glycols (10% w/w). The ratio of dielectric constant (ε) to dynamic viscosity (η) of TEG, DEG, and EG, respectively, is 0.48, 0.89, and 2.28 that is due to improvement of anodized aluminum in the presence glycol derivatives as EG > DEG > TEG.

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来源期刊
CiteScore
1.60
自引率
11.10%
发文量
63
审稿时长
2-4 weeks
期刊介绍: Russian Journal of Applied Chemistry (Zhurnal prikladnoi khimii) was founded in 1928. It covers all application problems of modern chemistry, including the structure of inorganic and organic compounds, kinetics and mechanisms of chemical reactions, problems of chemical processes and apparatus, borderline problems of chemistry, and applied research.
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