新型高熵合金(NbTi)$_{0.67}$$(MoHfV)$_{0.33}$$的超导性

Wojciech Nowak, Bartosz Rusin, Michał Babij, Rafał Topolnicki, Tomasz Ossowski, Adam Pikul, Rafał Idczak
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摘要

研究人员测定了一种新型富铌钛高熵合金(NbTi)\(_{\text {0.67}}\)(MoHfV)\(_{\text {0.33}}\)的结构和超导特性。合金是通过电弧熔炼合成的,其物理性质通过 X 射线粉末衍射、能量色散 X 射线光谱、磁化、电阻率和比热测量来表征。实验数据显示,(NbTi)\(_{text {0.67}}\)(MoHfV)\(_{\text {0.33}}\)以体心立方结构结晶,并在约 5 K 以下表现出 II 型超导性。他们的研究结果表明,就 HEAs 而言,在接近 E\(_{\mathrm {text {F}}\) 的能量区域,局部原子构型对其电子结构的影响相当小,甚至可以忽略不计。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Superconductivity in a New High-Entropy Alloy (NbTi) $$_{0.67}$$ (MoHfV) $$_{0.33}$$

The structural and superconducting properties of a new niobium- and titanium-rich high-entropy alloy (NbTi)\(_{\text {0.67}}\)(MoHfV)\(_{\text {0.33}}\) were determined. The alloy was synthesized by arc melting and its physical properties were characterized by means of X-ray powder diffraction, energy dispersive X-ray spectroscopy, magnetization, electrical resistivity and specific heat measurements. Experimental data revealed that the (NbTi)\(_{\text {0.67}}\)(MoHfV)\(_{\text {0.33}}\) crystalizes in body-centered cubic structure and exhibits type-II superconductivity below about 5 K. In addition, electronic structure calculations were performed using the Density Functional Theory (DFT) method. Their results suggest that in case of HEAs, the influence of the local atomic configuration on their electronic structure in the energy region close to E\(_{\mathrm {\text {F}}}\) is rather small or even negligible.

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