用于识别 Fe3+ 的 Ixora coccinea 花衍生绿色发光碳量子点以及制备用于铃木-宫浦偶联和氰化过程的 Pd 纳米粒子

IF 2.7 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY New Journal of Chemistry Pub Date : 2024-06-26 DOI:10.1039/D4NJ02217C
Namrata Priyadarshini Hota and Sathiyanarayanan Kulathu Iyer
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摘要

我们采用溶热法从 Ixora coccinea 花和邻苯二胺中制备出了高量子产率(43%)的球形高荧光微小形状(约 3 nm)氮掺杂碳量子点(NCQDs)。由于这种 NCQD 具有依赖激发的荧光活性,因此它被用来实时选择性地检测人体血清中的 Fe3+ 离子,因为它是人体血液的一种成分。结果发现,NCQD 的检测限(LOD)为 60nM。我们还利用 NCQD 合成了钯纳米粒子,无需额外的还原剂或稳定剂,因为这些量子点同时具有还原剂和稳定剂的作用。我们使用了大量的表征技术对纳米粒子进行表征,所有表征结果都表明,NCQD 的存在稳定了纳米粒子。钯纳米粒子尺寸小(4 nm),比表面积大(35.77 m2/g),因此在铃木-米亚乌拉偶联和氰化过程中具有很强的催化活性。显然,合成的钯纳米粒子和 NCQD 分别在催化和传感领域具有多种用途。
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Ixora coccinea flower-derived green luminescent carbon quantum dots for Fe3+ recognition and preparation of Pd nanoparticles for the Suzuki–Miyaura coupling and cyanation process†

The solvothermal method of producing spherically shaped and highly fluorescent tiny (∼3 nm) nitrogen-doped carbon quantum dots (NCQDs) with high quantum yield (43%) from Ixora coccinea flowers and o-phenylenediamine has been approached sustainably. Since these NCQDs exhibit excitation-dependent fluorescence activity, they were used to detect the Fe3+ ion selectively in real-time in human blood serum, because it is a component of human blood. The limit of detection (LOD) of the NCQDs was found to be 60 nM. We also synthesized palladium nanoparticles utilizing the NCQDs without additional reducing or stabilizing agents because these quantum dots serve as both. Numerous characterization techniques were used to characterize the nanoparticles, and all the characterizations showed the presence of NCQDs, which stabilize the nanoparticles. Palladium nanoparticles’ small size (4 nm) and large surface area (35.77 m2 g−1) enable them to exhibit strong catalytic activity in Suzuki–Miyaura coupling and cyanation processes. It is obvious that synthetic palladium nanoparticles and NCQDs have a variety of uses in the fields of catalysis and sensing respectively.

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来源期刊
New Journal of Chemistry
New Journal of Chemistry 化学-化学综合
CiteScore
5.30
自引率
6.10%
发文量
1832
审稿时长
2 months
期刊介绍: A journal for new directions in chemistry
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