{"title":"用于光学防伪的、随激发波长变化的可调色 Te4+掺杂 Cs2ZrCl6 空位有序包晶石","authors":"Yu Qi, Chengyue Xin, Wenjun Zhang, Zhongfa Li, Zihan Chen and Zhongyu Duan","doi":"10.1039/D4NJ01645A","DOIUrl":null,"url":null,"abstract":"<p >Te<small><sup>4+</sup></small>-doped Cs<small><sub>2</sub></small>ZrCl<small><sub>6</sub></small> vacancy-ordered perovskites with excitation wavelength-dependent tunable color have been synthesised by a simple precipitation method at room temperature, with two luminescent centres originating from the Te<small><sup>4+</sup></small> and the STE (self-trapping exciton) of the Cs<small><sub>2</sub></small>ZrCl<small><sub>6</sub></small> itself, respectively. They exhibit two different emission characteristics at 254 nm and 365 nm excitation wavelengths. At an excitation wavelength of 254 nm, the emission characteristics allow Te<small><sup>4+</sup></small>-doped Cs<small><sub>2</sub></small>ZrCl<small><sub>6</sub></small> to exhibit tunable emission from blue to white to yellow under the control of Te<small><sup>4+</sup></small> doping. And the excitation wavelength of 365 nm shows yellow emission. Te<small><sup>4+</sup></small> doped Cs<small><sub>2</sub></small>ZrCl<small><sub>6</sub></small> phosphors were used for optical anti-counterfeiting, and the anti-counterfeiting patterns were well distinguished under 254 nm and 365 nm UV lamps, demonstrating the potential of this excitation wavelength-dependent tunable color material for optical anti-counterfeiting applications.</p>","PeriodicalId":95,"journal":{"name":"New Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Excitation wavelength-dependent tunable color Te4+-doped Cs2ZrCl6 vacancy-ordered perovskites for optical anti-counterfeiting†\",\"authors\":\"Yu Qi, Chengyue Xin, Wenjun Zhang, Zhongfa Li, Zihan Chen and Zhongyu Duan\",\"doi\":\"10.1039/D4NJ01645A\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Te<small><sup>4+</sup></small>-doped Cs<small><sub>2</sub></small>ZrCl<small><sub>6</sub></small> vacancy-ordered perovskites with excitation wavelength-dependent tunable color have been synthesised by a simple precipitation method at room temperature, with two luminescent centres originating from the Te<small><sup>4+</sup></small> and the STE (self-trapping exciton) of the Cs<small><sub>2</sub></small>ZrCl<small><sub>6</sub></small> itself, respectively. They exhibit two different emission characteristics at 254 nm and 365 nm excitation wavelengths. At an excitation wavelength of 254 nm, the emission characteristics allow Te<small><sup>4+</sup></small>-doped Cs<small><sub>2</sub></small>ZrCl<small><sub>6</sub></small> to exhibit tunable emission from blue to white to yellow under the control of Te<small><sup>4+</sup></small> doping. And the excitation wavelength of 365 nm shows yellow emission. Te<small><sup>4+</sup></small> doped Cs<small><sub>2</sub></small>ZrCl<small><sub>6</sub></small> phosphors were used for optical anti-counterfeiting, and the anti-counterfeiting patterns were well distinguished under 254 nm and 365 nm UV lamps, demonstrating the potential of this excitation wavelength-dependent tunable color material for optical anti-counterfeiting applications.</p>\",\"PeriodicalId\":95,\"journal\":{\"name\":\"New Journal of Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-06-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"New Journal of Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/nj/d4nj01645a\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"New Journal of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/nj/d4nj01645a","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Excitation wavelength-dependent tunable color Te4+-doped Cs2ZrCl6 vacancy-ordered perovskites for optical anti-counterfeiting†
Te4+-doped Cs2ZrCl6 vacancy-ordered perovskites with excitation wavelength-dependent tunable color have been synthesised by a simple precipitation method at room temperature, with two luminescent centres originating from the Te4+ and the STE (self-trapping exciton) of the Cs2ZrCl6 itself, respectively. They exhibit two different emission characteristics at 254 nm and 365 nm excitation wavelengths. At an excitation wavelength of 254 nm, the emission characteristics allow Te4+-doped Cs2ZrCl6 to exhibit tunable emission from blue to white to yellow under the control of Te4+ doping. And the excitation wavelength of 365 nm shows yellow emission. Te4+ doped Cs2ZrCl6 phosphors were used for optical anti-counterfeiting, and the anti-counterfeiting patterns were well distinguished under 254 nm and 365 nm UV lamps, demonstrating the potential of this excitation wavelength-dependent tunable color material for optical anti-counterfeiting applications.