L. Yu. Yarullin, V. F. Khairutdinov, F. R. Gabitov, I. Z. Salikhov, L. Yu. Sabirova, I. Sh. Khabriev, I. M. Abdulagatov
{"title":"用动态法测定物质在超临界二氧化碳中溶解度的实验装置","authors":"L. Yu. Yarullin, V. F. Khairutdinov, F. R. Gabitov, I. Z. Salikhov, L. Yu. Sabirova, I. Sh. Khabriev, I. M. Abdulagatov","doi":"10.1134/S0020441224700301","DOIUrl":null,"url":null,"abstract":"<p>An experimental setup was created to measure the solubility of substances in supercritical carbon dioxide by a dynamic method, including the possibility of adding a cosolvent to the main solvent: CO<sub>2</sub>. A new technique has been developed for determining the mass amount of supercritical carbon dioxide that has passed during the experiment, which is important in determining solubility. Experimental data on the solubility of diphenyl in supercritical carbon dioxide are obtained, which are in good agreement with the literature data, at various state parameters: temperature and pressure. The experimental setup will make it possible to obtain new experimental data in the future on the solubility of a wide range of substances in supercritical carbon dioxide as well as in supercritical carbon dioxide with various organic cosolvents.</p>","PeriodicalId":587,"journal":{"name":"Instruments and Experimental Techniques","volume":"67 1","pages":"163 - 169"},"PeriodicalIF":0.4000,"publicationDate":"2024-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Experimental Setup for Measuring the Solubility of Substances in Supercritical Carbon Dioxide by the Dynamic Method\",\"authors\":\"L. Yu. Yarullin, V. F. Khairutdinov, F. R. Gabitov, I. Z. Salikhov, L. Yu. Sabirova, I. Sh. Khabriev, I. M. Abdulagatov\",\"doi\":\"10.1134/S0020441224700301\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>An experimental setup was created to measure the solubility of substances in supercritical carbon dioxide by a dynamic method, including the possibility of adding a cosolvent to the main solvent: CO<sub>2</sub>. A new technique has been developed for determining the mass amount of supercritical carbon dioxide that has passed during the experiment, which is important in determining solubility. Experimental data on the solubility of diphenyl in supercritical carbon dioxide are obtained, which are in good agreement with the literature data, at various state parameters: temperature and pressure. The experimental setup will make it possible to obtain new experimental data in the future on the solubility of a wide range of substances in supercritical carbon dioxide as well as in supercritical carbon dioxide with various organic cosolvents.</p>\",\"PeriodicalId\":587,\"journal\":{\"name\":\"Instruments and Experimental Techniques\",\"volume\":\"67 1\",\"pages\":\"163 - 169\"},\"PeriodicalIF\":0.4000,\"publicationDate\":\"2024-06-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Instruments and Experimental Techniques\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0020441224700301\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ENGINEERING, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Instruments and Experimental Techniques","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1134/S0020441224700301","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENGINEERING, MULTIDISCIPLINARY","Score":null,"Total":0}
Experimental Setup for Measuring the Solubility of Substances in Supercritical Carbon Dioxide by the Dynamic Method
An experimental setup was created to measure the solubility of substances in supercritical carbon dioxide by a dynamic method, including the possibility of adding a cosolvent to the main solvent: CO2. A new technique has been developed for determining the mass amount of supercritical carbon dioxide that has passed during the experiment, which is important in determining solubility. Experimental data on the solubility of diphenyl in supercritical carbon dioxide are obtained, which are in good agreement with the literature data, at various state parameters: temperature and pressure. The experimental setup will make it possible to obtain new experimental data in the future on the solubility of a wide range of substances in supercritical carbon dioxide as well as in supercritical carbon dioxide with various organic cosolvents.
期刊介绍:
Instruments and Experimental Techniques is an international peer reviewed journal that publishes reviews describing advanced methods for physical measurements and techniques and original articles that present techniques for physical measurements, principles of operation, design, methods of application, and analysis of the operation of physical instruments used in all fields of experimental physics and when conducting measurements using physical methods and instruments in astronomy, natural sciences, chemistry, biology, medicine, and ecology.