用动态法测定物质在超临界二氧化碳中溶解度的实验装置

IF 0.4 4区 工程技术 Q4 ENGINEERING, MULTIDISCIPLINARY Instruments and Experimental Techniques Pub Date : 2024-06-28 DOI:10.1134/s0020441224700301
L. Yu. Yarullin, V. F. Khairutdinov, F. R. Gabitov, I. Z. Salikhov, L. Yu. Sabirova, I. Sh. Khabriev, I. M. Abdulagatov
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引用次数: 0

摘要

摘要 建立了一个实验装置,通过动态方法测量物质在超临界二氧化碳中的溶解度,包括在主溶剂中添加共溶剂的可能性:二氧化碳。我们还开发了一种新技术,用于确定实验过程中流过的超临界二氧化碳的质量,这对确定溶解度非常重要。获得了二苯基在超临界二氧化碳中溶解度的实验数据,这些数据与文献数据在不同状态参数(温度和压力)下的数据十分吻合。该实验装置将使我们有可能在未来获得关于多种物质在超临界二氧化碳中的溶解度以及在超临界二氧化碳与各种有机助溶剂中的溶解度的新实验数据。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Experimental Setup for Measuring the Solubility of Substances in Supercritical Carbon Dioxide by the Dynamic Method

Abstract

An experimental setup was created to measure the solubility of substances in supercritical carbon dioxide by a dynamic method, including the possibility of adding a cosolvent to the main solvent: CO2. A new technique has been developed for determining the mass amount of supercritical carbon dioxide that has passed during the experiment, which is important in determining solubility. Experimental data on the solubility of diphenyl in supercritical carbon dioxide are obtained, which are in good agreement with the literature data, at various state parameters: temperature and pressure. The experimental setup will make it possible to obtain new experimental data in the future on the solubility of a wide range of substances in supercritical carbon dioxide as well as in supercritical carbon dioxide with various organic cosolvents.

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来源期刊
Instruments and Experimental Techniques
Instruments and Experimental Techniques 工程技术-工程:综合
CiteScore
1.20
自引率
33.30%
发文量
113
审稿时长
4-8 weeks
期刊介绍: Instruments and Experimental Techniques is an international peer reviewed journal that publishes reviews describing advanced methods for physical measurements and techniques and original articles that present techniques for physical measurements, principles of operation, design, methods of application, and analysis of the operation of physical instruments used in all fields of experimental physics and when conducting measurements using physical methods and instruments in astronomy, natural sciences, chemistry, biology, medicine, and ecology.
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