1,2-双（苯磺酰基）乙烯 (BPSE)：可用于基于自由基和电子转移的有机合成的强效自由基 C2 合成物

Synthesis Pub Date : 2024-07-01 DOI:10.1055/s-0043-1775374

Shuhei Sumino, Ilhyong Ryu, Frédéric Robert, Yannick Landais

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摘要

在这篇短评中，我们将讨论使用 1,2-双（苯磺酰基）乙烯（BPSE）的自由基反应，BPSE 作为一种用于（苯磺酰基）乙烯基化反应的多功能构筑基块，已经引起了广泛关注。无论其 E 形还是 Z 形，BPSE 在烷基和芳基自由基的攻击下都能表现出可靠的反应活性，从而成为可靠的自由基 C2 合物。1 引言 2 在自由基链反应中的应用 3 在利用电子转移过程的反应中的应用 4 在基于自由基的 C-H 烯化反应中的应用 5 结论

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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1,2-Bis(phenylsulfonyl)ethylene (BPSE): A Potent Radical C2 Synthon Available in the Radical and Electron-Transfer-Based Organic Synthesis

In this Short Review, we discuss radical reactions using 1,2-bis(phenylsulfonyl)ethylene (BPSE), which has drawn significant attention as a versatile building block for (phenylsulfonyl)ethenylation. Regardless of its E or Z form, BPSE exhibits reliable reactivity towards the attack of alkyl and aryl radicals in order to function as a reliable radical C2 synthon.

1 Introduction

2 Use in Radical Chain Reactions

3 Use in Reactions Utilizing an Electron-Transfer Process

4 Use in Radical-Based C–H Alkenylation

5 Conclusion

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