Aixin Cui, Man Wu, Tuo Guo, Xiunan Sun, Yulong Chen, Qingjie Guo
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引用次数: 0
摘要
氢化二氧化碳生产轻烯烃是一条极具前景的烯烃合成路线。然而,实现高产的前提是开发出一种具有高转化率、高选择性和高稳定性的催化剂。本文报告了一种 Ca2-xKxFe2O5 催化剂,其 CO2 转化率高达 46%,轻烯烃选择性为 34.59%,烯烃-烷烃摩尔比为 8.31。Ca 的加入增加了催化剂的氧空位浓度和强碱性位点,从而改善了 HCOO* 中间体的形成,提高了 CO 的选择性和 CO2 转化率。同时,K 的加入进一步提高了 CO2 转化率,并通过促进 C-C 偶联提高了轻烯烃的选择性。此外,Ca1.0K1.0Fe2O5 催化剂在 72 小时内没有出现明显的失活现象,这表明该催化剂具有很强的工业潜力。
Potassium-modified calcium-ferrate-catalyzed hydrogenation of carbon dioxide to produce light olefins
Hydrogenating CO2 to produce light olefins is a highly promising route for olefin synthesis. However, the premise of achieving a high yield is to develop a catalyst with a high conversion rate, selectivity, and stability. This paper reports a Ca2−xKxFe2O5 catalyst with an CO2 conversion of up to 46%, a light olefin selectivity of 34.59%, and an olefin-alkane molar ratio of 8.31. Ca addition increased the oxygen vacancy concentration and strong basic sites of the catalyst, resulting in improved HCOO* intermediate formation, better CO selectivity, and higher CO2 conversion rates. Meanwhile, the addition of K further enhanced the rate of CO2 conversion while also improving the selectivity of light olefins by promoting C–C coupling. Furthermore, the Ca1.0K1.0Fe2O5 catalyst demonstrated no notable deactivation over a period of 72 h, indicating the strong industrial potential of this catalyst.