以甘蔗为原料生产山梨醇和衣康酸的技术经济学和环境评估

IF 4.1 2区 工程技术 Q2 ENGINEERING, CHEMICAL Chemical Engineering Science Pub Date : 2024-06-27 DOI:10.1016/j.ces.2024.120431
Cara van Heerden, Catharine Elizabeth Bosman, Somayeh Farzad, Johann Ferdinand Görgens
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引用次数: 0

摘要

通过 Aspen Plus® 模拟、技术经济和环境评估,研究了在能源自给自足的生物炼制方案中利用甘蔗原料生产山梨醇或衣康酸的情况。与 A-淀粉中的果糖共同生产的山梨醇的最低销售价格(MSP)(0.81 美元/千克)与技术级山梨醇的市场价格(0.5 至 1.1 美元/千克)相近,内部收益率(IRR)为 19.65%。用 A-淀粉与甘露醇联合生产的山梨醇的最大生产成本较低(0.48 美元/千克),低于食品级山梨醇的价格(0.58 美元/千克),内部收益率较高(23.63%)。将 A-沼渣与木质纤维素结合起来共同生产山梨醇和甘露醇,可使 MSP(0.63 美元/千克)高于市场价格,并降低内部收益率(18.46%)。该方案的温室气体排放量也低于仅使用 A-蔗糖的方案,主要原因是采用了制氢方法。由于内部收益率较低(4.49% 至 11.61%),在类似方案中利用甘蔗原料生产衣康酸的方案缺乏吸引力。
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Techno-economics and environmental assessment of sorbitol and itaconic acid production from sugarcane-based feedstock

Production of sorbitol or itaconic acid from sugarcane feedstocks in energy self-sufficient biorefinery scenarios were investigated, via Aspen Plus® simulations, techno-economic and environmental assessments. Sorbitol co-produced with fructose from A-molasses had a minimum selling price (MSP) (0.81 $/kg) similar to technical-grade sorbitol market prices (0.5 to 1.1 $/kg), and an internal rate of return (IRR) of 19.65%. Sorbitol co-produced with mannitol from A-molasses had a lower MSP (0.48 $/kg), below food-grade sorbitol prices (0.58 $/kg) and a higher IRR (23.63%). Combining A-molasses with lignocelluloses for the co-production of sorbitol and mannitol increased the MSP (0.63 $/kg) above the market price and decreased the IRR (18.46%). This scenario also had greenhouse gas emissions lower than that of its A-molasses only counterpart, mainly due to the method of hydrogen production. Itaconic acid production from sugarcane feedstocks in similar scenarios was unattractive due to lower IRRs (4.49% to 11.61%).

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来源期刊
Chemical Engineering Science
Chemical Engineering Science 工程技术-工程:化工
CiteScore
7.50
自引率
8.50%
发文量
1025
审稿时长
50 days
期刊介绍: Chemical engineering enables the transformation of natural resources and energy into useful products for society. It draws on and applies natural sciences, mathematics and economics, and has developed fundamental engineering science that underpins the discipline. Chemical Engineering Science (CES) has been publishing papers on the fundamentals of chemical engineering since 1951. CES is the platform where the most significant advances in the discipline have ever since been published. Chemical Engineering Science has accompanied and sustained chemical engineering through its development into the vibrant and broad scientific discipline it is today.
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