Tian Tian, Wanting Wang, Kexin Li, Yiping Wang, Wensheng Fu
{"title":"合理设计嵌入掺氮碳框架的钌/钴纳米粒子,将其作为用于多巴胺检测和有机污染物降解的多功能纳米酶","authors":"Tian Tian, Wanting Wang, Kexin Li, Yiping Wang, Wensheng Fu","doi":"10.1016/j.jallcom.2024.175429","DOIUrl":null,"url":null,"abstract":"Exploring efficient multi-functional catalysts with is critical for oxidase-like catalysis and environmental pollutant degradation. In this paper, we report a RuCo alloy embedded in a nitrogen-doped carbon matrix (RuCo@NC) derived from a Co-based metal-organic framework (ZIF-67). RuCo@NC exhibits highly efficient oxidase activity for dopamine (DA) detection, excellent activity for 4-nitrophenol (4-NP) reduction to the higher valued 4-aminophenol (4-AP) with the addition of NaBH solution, and remarkable activity for rhodamine B (RhB) degradation with the addition of the NaBH. Owing to the presence of the reactive oxygen species •OH, the oxidase-like activity of RuCo@NC is increased by 1.94 times that of bare Co@NC. RuCo@NC exhibits superior activity for the 4-NP reduction with a high turnover frequency (TOF) of 1.04×10 mmol mg min. Moreover, when RuCo@NC is employed for RhB degradation with NaBH, the efficiency of the system can reach 93.8 %.","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":null,"pages":null},"PeriodicalIF":5.8000,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Rational design of Ruthenium/Cobalt nanoparticles embedded in nitrogen-doped carbon frameworks as a multifunctional nanozyme for dopamine detection and organic pollutant degradation\",\"authors\":\"Tian Tian, Wanting Wang, Kexin Li, Yiping Wang, Wensheng Fu\",\"doi\":\"10.1016/j.jallcom.2024.175429\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Exploring efficient multi-functional catalysts with is critical for oxidase-like catalysis and environmental pollutant degradation. In this paper, we report a RuCo alloy embedded in a nitrogen-doped carbon matrix (RuCo@NC) derived from a Co-based metal-organic framework (ZIF-67). RuCo@NC exhibits highly efficient oxidase activity for dopamine (DA) detection, excellent activity for 4-nitrophenol (4-NP) reduction to the higher valued 4-aminophenol (4-AP) with the addition of NaBH solution, and remarkable activity for rhodamine B (RhB) degradation with the addition of the NaBH. Owing to the presence of the reactive oxygen species •OH, the oxidase-like activity of RuCo@NC is increased by 1.94 times that of bare Co@NC. RuCo@NC exhibits superior activity for the 4-NP reduction with a high turnover frequency (TOF) of 1.04×10 mmol mg min. Moreover, when RuCo@NC is employed for RhB degradation with NaBH, the efficiency of the system can reach 93.8 %.\",\"PeriodicalId\":344,\"journal\":{\"name\":\"Journal of Alloys and Compounds\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.8000,\"publicationDate\":\"2024-07-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Alloys and Compounds\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1016/j.jallcom.2024.175429\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Alloys and Compounds","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1016/j.jallcom.2024.175429","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Rational design of Ruthenium/Cobalt nanoparticles embedded in nitrogen-doped carbon frameworks as a multifunctional nanozyme for dopamine detection and organic pollutant degradation
Exploring efficient multi-functional catalysts with is critical for oxidase-like catalysis and environmental pollutant degradation. In this paper, we report a RuCo alloy embedded in a nitrogen-doped carbon matrix (RuCo@NC) derived from a Co-based metal-organic framework (ZIF-67). RuCo@NC exhibits highly efficient oxidase activity for dopamine (DA) detection, excellent activity for 4-nitrophenol (4-NP) reduction to the higher valued 4-aminophenol (4-AP) with the addition of NaBH solution, and remarkable activity for rhodamine B (RhB) degradation with the addition of the NaBH. Owing to the presence of the reactive oxygen species •OH, the oxidase-like activity of RuCo@NC is increased by 1.94 times that of bare Co@NC. RuCo@NC exhibits superior activity for the 4-NP reduction with a high turnover frequency (TOF) of 1.04×10 mmol mg min. Moreover, when RuCo@NC is employed for RhB degradation with NaBH, the efficiency of the system can reach 93.8 %.
期刊介绍:
The Journal of Alloys and Compounds is intended to serve as an international medium for the publication of work on solid materials comprising compounds as well as alloys. Its great strength lies in the diversity of discipline which it encompasses, drawing together results from materials science, solid-state chemistry and physics.