A. M. Cheplakova, E. A. Eliseev, D. G. Samsonenko, V. P. Fedin
{"title":"基于镁阳离子和异构四氟苯二甲酸配体的金属有机框架的晶体结构","authors":"A. M. Cheplakova, E. A. Eliseev, D. G. Samsonenko, V. P. Fedin","doi":"10.1134/S0022476624060106","DOIUrl":null,"url":null,"abstract":"<p>Coordination polymers [Mg(EtOH)<sub>3</sub>(H<sub>2</sub>O)(1,3-<i>t</i>FBDC)]·EtOH (<b>1</b>), [Mg(MeOH)<sub>2</sub>(1,2-<i>t</i>FBDC)] (<b>2</b>), [{Mg(H<sub>2</sub>O)<sub>2</sub>(EtOH)<sub>2</sub>}Mg(1,2-<i>t</i>FBDC)<sub>2</sub>] (<b>3</b>), and [Mg(EtOH)<sub>2</sub>(1,4-<i>t</i>FBDC)] (<b>4</b>) are obtained in the interaction of magnesium hydroxide with various isomers of tetrafluorobenzene dicarboxylic acid (phthalic, isophthalic, and terephthalic; H<sub>2</sub>tFBDC) in alcohol solutions (MeOH or EtOH). The compositions and structures of these compounds are determined by single crystal X-ray diffraction. Compound <b>1</b> is a chain coordination polymer; compounds <b>2</b>–<b>4</b> have layered structures.</p>","PeriodicalId":668,"journal":{"name":"Journal of Structural Chemistry","volume":"65 6","pages":"1219 - 1226"},"PeriodicalIF":1.4000,"publicationDate":"2024-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Crystal Structures of Metal-Organic Frameworks Based on Magnesium Cations and Isomeric Tetrafluorobenzenedicarboxylate Ligands\",\"authors\":\"A. M. Cheplakova, E. A. Eliseev, D. G. Samsonenko, V. P. Fedin\",\"doi\":\"10.1134/S0022476624060106\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Coordination polymers [Mg(EtOH)<sub>3</sub>(H<sub>2</sub>O)(1,3-<i>t</i>FBDC)]·EtOH (<b>1</b>), [Mg(MeOH)<sub>2</sub>(1,2-<i>t</i>FBDC)] (<b>2</b>), [{Mg(H<sub>2</sub>O)<sub>2</sub>(EtOH)<sub>2</sub>}Mg(1,2-<i>t</i>FBDC)<sub>2</sub>] (<b>3</b>), and [Mg(EtOH)<sub>2</sub>(1,4-<i>t</i>FBDC)] (<b>4</b>) are obtained in the interaction of magnesium hydroxide with various isomers of tetrafluorobenzene dicarboxylic acid (phthalic, isophthalic, and terephthalic; H<sub>2</sub>tFBDC) in alcohol solutions (MeOH or EtOH). The compositions and structures of these compounds are determined by single crystal X-ray diffraction. Compound <b>1</b> is a chain coordination polymer; compounds <b>2</b>–<b>4</b> have layered structures.</p>\",\"PeriodicalId\":668,\"journal\":{\"name\":\"Journal of Structural Chemistry\",\"volume\":\"65 6\",\"pages\":\"1219 - 1226\"},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2024-07-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Structural Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0022476624060106\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Structural Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0022476624060106","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Crystal Structures of Metal-Organic Frameworks Based on Magnesium Cations and Isomeric Tetrafluorobenzenedicarboxylate Ligands
Coordination polymers [Mg(EtOH)3(H2O)(1,3-tFBDC)]·EtOH (1), [Mg(MeOH)2(1,2-tFBDC)] (2), [{Mg(H2O)2(EtOH)2}Mg(1,2-tFBDC)2] (3), and [Mg(EtOH)2(1,4-tFBDC)] (4) are obtained in the interaction of magnesium hydroxide with various isomers of tetrafluorobenzene dicarboxylic acid (phthalic, isophthalic, and terephthalic; H2tFBDC) in alcohol solutions (MeOH or EtOH). The compositions and structures of these compounds are determined by single crystal X-ray diffraction. Compound 1 is a chain coordination polymer; compounds 2–4 have layered structures.
期刊介绍：
Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
