用于改善接受污水处理厂废水的淡水溪流水质的生物聚合物复合柱

IF 4.7 3区 工程技术 Q2 ENGINEERING, ENVIRONMENTAL Journal of Polymers and the Environment Pub Date : 2024-07-09 DOI:10.1007/s10924-024-03335-0
Şahin Akpınar, Fatma Gurbuz, Samet Özcan, Mehmet Odabaşı
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引用次数: 0

摘要

未经充分处理的废水含有高浓度的污染物,当它与河流和湖泊的清洁水混合时,就会造成危害。尤其是硝酸盐,它是导致富营养化的一个主要全球性问题,对水生生态系统和人类健康都构成威胁。为解决这一问题,本研究评估了聚合物低温凝胶(PC)和生物聚合物(EPS)混合复合材料(EPS@PC)去除硝酸盐的效率。此外,还对安卡拉溪流的实际水样中磷酸盐、氯离子和化学需氧量(COD)的减少情况进行了量化测试,安卡拉溪流同时接收来自城市(UWTP)和工业(IWTP)污水处理厂的污水。我们制备了五种不同吸附性能的柱,其中一些还与铁结合在一起。与其他测试柱相比,EPS-@PC-C5 柱的硝酸盐去除吸附率最高。EPS@PC-C5 的硝酸盐去除效率高达 126.38 毫克/克,COD 的去除率为 60.2% 至 94.1%。氯化物浓度的去除率在 56.0% 到 75.7% 之间,而磷酸盐的去除率则在 87% 到 99% 之间。由带负电荷和正电荷配体的 EPS(EPS@PC)组成的色谱柱是可靠和合适的水处理选择。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Biopolymeric Composite Columns for Improving Water Quality in a Freshwater Stream Receiving Wastewater Treatment Plant Effluents

Inefficiently treated wastewater, which contains a high concentration of pollutants, is hazardous when it is mixed with the clean water of rivers and lakes. Nitrate in particular is a major global problem that leads to eutrophication and poses a threat to both aquatic ecosystems and human health. To address this issue, this work assessed the efficiency of polymeric cryogel (PC) and biopolymer (EPS)-blended composites (EPS@PC) in removing nitrates. Tests were also conducted to quantify the decrease in phosphate, chloride ions, and chemical oxygen demand (COD) in real water samples taken from the Ankara stream, which receives effluents from both urban (UWTP) and industrial (IWTP) wastewater treatment plants. Five different columns with varying adsorptive properties were prepared, some of which were combined with iron. The EPS-@PC-C5 column demonstrated the highest adsorption ratio for nitrate removal compared to the other tested columns. The EPS@PC-C5 achieved a high removal efficiency of 126.38 mg nitrate/g and showed COD reduction ranging from 60.2 to 94.1%. The removal ratio of chloride concentration varied between 56.0 and 75.7%, while the removal of phosphates ranged from 87 to 99%. Columns composed of EPS (EPS@PC) with both negatively and positively charged ligands are dependable and suitable options for water remediation.

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来源期刊
Journal of Polymers and the Environment
Journal of Polymers and the Environment 工程技术-高分子科学
CiteScore
9.50
自引率
7.50%
发文量
297
审稿时长
9 months
期刊介绍: The Journal of Polymers and the Environment fills the need for an international forum in this diverse and rapidly expanding field. The journal serves a crucial role for the publication of information from a wide range of disciplines and is a central outlet for the publication of high-quality peer-reviewed original papers, review articles and short communications. The journal is intentionally interdisciplinary in regard to contributions and covers the following subjects - polymers, environmentally degradable polymers, and degradation pathways: biological, photochemical, oxidative and hydrolytic; new environmental materials: derived by chemical and biosynthetic routes; environmental blends and composites; developments in processing and reactive processing of environmental polymers; characterization of environmental materials: mechanical, physical, thermal, rheological, morphological, and others; recyclable polymers and plastics recycling environmental testing: in-laboratory simulations, outdoor exposures, and standardization of methodologies; environmental fate: end products and intermediates of biodegradation; microbiology and enzymology of polymer biodegradation; solid-waste management and public legislation specific to environmental polymers; and other related topics.
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