Dy3+ 激活的 CaY2O4 磷光体发出的白光

IF 0.4 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Russian Physics Journal Pub Date : 2024-07-08 DOI:10.1007/s11182-024-03209-x
Piya Rani Talukdar, Vikas Dubey, Janita Saji, M. C. Rao
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引用次数: 0

摘要

报告了一种 Dy3+ 活性氧化钙钇(CaY2O4)荧光粉的合成和表征。CaY2O4:Dy3+ (1.5 mol%)荧光粉是利用改良的固态反应技术进行煅烧和烧结合成的。X 射线衍射技术揭示了其立方结构。利用 FEGSEM 技术研究了所制备荧光粉的形貌和粒度分布。傅立叶变换红外光谱确认了化学键和官能团分析。对 CaY2O4:Dy3+ 荧光粉进行的光致发光分析表明,在 285 和 348 纳米波长处存在双激发波长,尤其是在紫外区。在 383 纳米波长处,发现了三个不同的发射峰,分别位于 238、485 和 571 纳米波长处。光谱参数是通过 CIE 色度坐标计算得出的。镝离子激活的 CaY2O4 荧光粉(1.5 摩尔%)的 CIE 坐标显示,其发射接近色度图的白光区域,这表明它适用于 W-LED 应用。
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White Light Emission from Dy3+-Activated CaY2O4 Phosphor

Synthesis and characterization of a Dy3+-activated calcium yttrium oxide (CaY2O4) phosphor are reported. The CaY2O4:Dy3+ (1.5 mol%) phosphor is synthesized using a modified solid-state reaction technique for calcination and sintering. The cubic structure is revealed by the X-ray diffraction technique. The morphology and particle size distribution of the prepared phosphor are investigated by the FEGSEM technique. The chemical bonds and functional group analysis are confirmed by the FTIR. A photoluminescence analysis of the CaY2O4:Dy3+ phosphor shows dual excitation wavelengths at 285 and 348 nm, especially in the ultraviolet region. At 383 nm, three distinct emission peaks are found at the wavelengths 238, 485, and 571 nm. The spectroscopic parameters are calculated using the CIE chromaticity coordinates. The CIE coordinates of the Dysprosium ion-activated CaY2O4 phosphor (1.5 mol%) show an emission near the white light region of the chromaticity diagram, suggesting that it is suitable for W-LED applications.

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来源期刊
Russian Physics Journal
Russian Physics Journal PHYSICS, MULTIDISCIPLINARY-
CiteScore
1.00
自引率
50.00%
发文量
208
审稿时长
3-6 weeks
期刊介绍: Russian Physics Journal covers the broad spectrum of specialized research in applied physics, with emphasis on work with practical applications in solid-state physics, optics, and magnetism. Particularly interesting results are reported in connection with: electroluminescence and crystal phospors; semiconductors; phase transformations in solids; superconductivity; properties of thin films; and magnetomechanical phenomena.
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