{"title":"电离能与水合能之间的相关性","authors":"Andrew Das Arulsamy","doi":"10.1007/s10953-024-01399-z","DOIUrl":null,"url":null,"abstract":"<div><p>Calculations of hydration energies are extremely important in physical, chemical, and life sciences, and therefore their values need to be accurately determined if these energies were to be used to derive the proper and correct physico-chemical mechanisms. Here, we prove the existence of absolute correlation between ionization and hydration energies for transition metal cations. The said absolute correlation can be exploited in an unambiguous manner to verify the calculated hydration energies for divalent and trivalent transition metal cations.</p></div>","PeriodicalId":666,"journal":{"name":"Journal of Solution Chemistry","volume":"53 12","pages":"1633 - 1650"},"PeriodicalIF":1.4000,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Correlation Between Ionization and Hydration Energies\",\"authors\":\"Andrew Das Arulsamy\",\"doi\":\"10.1007/s10953-024-01399-z\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Calculations of hydration energies are extremely important in physical, chemical, and life sciences, and therefore their values need to be accurately determined if these energies were to be used to derive the proper and correct physico-chemical mechanisms. Here, we prove the existence of absolute correlation between ionization and hydration energies for transition metal cations. The said absolute correlation can be exploited in an unambiguous manner to verify the calculated hydration energies for divalent and trivalent transition metal cations.</p></div>\",\"PeriodicalId\":666,\"journal\":{\"name\":\"Journal of Solution Chemistry\",\"volume\":\"53 12\",\"pages\":\"1633 - 1650\"},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2024-07-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Solution Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10953-024-01399-z\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Solution Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10953-024-01399-z","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Correlation Between Ionization and Hydration Energies
Calculations of hydration energies are extremely important in physical, chemical, and life sciences, and therefore their values need to be accurately determined if these energies were to be used to derive the proper and correct physico-chemical mechanisms. Here, we prove the existence of absolute correlation between ionization and hydration energies for transition metal cations. The said absolute correlation can be exploited in an unambiguous manner to verify the calculated hydration energies for divalent and trivalent transition metal cations.
期刊介绍:
Journal of Solution Chemistry offers a forum for research on the physical chemistry of liquid solutions in such fields as physical chemistry, chemical physics, molecular biology, statistical mechanics, biochemistry, and biophysics. The emphasis is on papers in which the solvent plays a dominant rather than incidental role. Featured topics include experimental investigations of the dielectric, spectroscopic, thermodynamic, transport, or relaxation properties of both electrolytes and nonelectrolytes in liquid solutions.