通过自发大气从烘干机棉绒中提取活性碳纤维用于超级电容器

IF 2.4 4区 化学 Q3 CHEMISTRY, PHYSICAL Ionics Pub Date : 2024-07-11 DOI:10.1007/s11581-024-05701-3
Victor Mshi Igba, M. A. Garcia-Lobato, Ulises Matías García-Pérez, E. Oyervides-Muñoz, Eder I. Martínez-Mora
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引用次数: 0

摘要

活性碳纤维(ACFs)是在自产生的气氛中利用烘干机棉绒微纤维通过简单的两步法合成的。在热解和活化过程中,根据布杜尔平衡原理创造了 CO/CO2 环境。生成的 ACF 具有高比表面积(1720 m2/g)、合适的孔径分布和良好的导电性(0.34-0.36 S/cm),从而促进了离子的快速转移。ACF 在 0.9 V 时的比电容高达 156.2,在 1 V 时的比电容高达 180.3 F/g。值得注意的是,ACF 具有出色的速率能力,功率密度超过 35 kW/kg,而且循环寿命延长,至少可充放电 104 次。这些结果可与在惰性气体环境下使用管式炉并控制加热斜坡的方法相媲美。
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Activated carbon fibers derived from dryer lint via self-generated atmosphere for supercapacitor applications

Activated carbon fibers (ACFs) were synthesized using a straightforward two-step process from dryer lint microfibers in a self-generated atmosphere. During pyrolysis and activation, a CO/CO2 environment was created based on the Boudouard equilibrium. The resulting ACFs showed a high specific surface area (1720 m2/g), a suitable pore size distribution, and good electrical conductivity (0.34–0.36 S/cm), promoting rapid ion transfer. ACFs demonstrated a high specific capacitance of 156.2 at 0.9 V and 180.3 F/g at 1 V. Notably, ACFs demonstrated outstanding rate capability with a power density exceeding 35 kW/kg, along with an extended cycle life of at least charge/discharge 104 cycles. These results are comparable to methods involving tube furnaces under inert gas with controlled heating ramps.

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来源期刊
Ionics
Ionics 化学-电化学
CiteScore
5.30
自引率
7.10%
发文量
427
审稿时长
2.2 months
期刊介绍: Ionics is publishing original results in the fields of science and technology of ionic motion. This includes theoretical, experimental and practical work on electrolytes, electrode, ionic/electronic interfaces, ionic transport aspects of corrosion, galvanic cells, e.g. for thermodynamic and kinetic studies, batteries, fuel cells, sensors and electrochromics. Fast solid ionic conductors are presently providing new opportunities in view of several advantages, in addition to conventional liquid electrolytes.
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