Altering the optical, physical, and TL Dosimetric properties of MgSO4:Dy2O3:B2O3 transparent glass ceramic system: Evaluating the impact of roughness control and ZnO inclusion

This research examines the influence of surface roughness and the incorporation of ZnO (0.05–0.20 mol%) on the magnesium sulfate: dysprosium oxide: boron oxide (0.1 < x < 0.5) glass ceramic system for dosimeter applications. The parent glasses were prepared using the melt-quenching technique, with all samples melted at 1350 °C, except for B, which was melted at 700 °C. The crystallization, roughness, and optical properties were further determined using X-ray Diffraction (XRD), Atomic Force Microscopy (AFM), and UV–Visible Spectrophotometry, respectively. The glass ceramics were exposed to 2.97 mGy of X-ray radiation ten cycles to assess specific dosimetric capabilities. Among the doped samples, MgSO₄:Dy₂O₃-(0.2B₂O₃:0.05ZnO) exhibited the most promising performance as a dosimeter. Notably, the Thermoluminescence Dosimetry (TLD) readings of the pre- and post-polished 0.2MDB were 1041.96 nC and 1278.84 nC, respectively, with roughness values of 1.83 nm and 54.7 nm. Similarly, the TLD readings of the pre- and post-polished 0.05MDBZ were 1888.33 nC and 3262.63 nC, respectively, with roughness values of 17.3 nm and 19.8 nm. This work highlights that surface roughness significantly enhances trapping efficiency, underscoring the importance of dosimeter polishing as a beneficial step in enhancing their performance.