Wanwu Ding, Mei Xu, Lumin Gou, Lingxia Li, Juan Ma, Jiazhi An, Xuefeng Lu, Xiaochun Liu, Xiaochun Li
{"title":"通过添加新型富 La 稀土晶粒细化剂细化次共晶 Al-7Si 合金的机制","authors":"Wanwu Ding, Mei Xu, Lumin Gou, Lingxia Li, Juan Ma, Jiazhi An, Xuefeng Lu, Xiaochun Liu, Xiaochun Li","doi":"10.1007/s11661-024-07510-9","DOIUrl":null,"url":null,"abstract":"<p>Refining the grain size of the as-casted hypoeutectic Al–Si alloys is an established technique for improving their mechanical properties. This work is based on the development of a novel La-riched grain refiner, <i>i.e.</i>, Al–3Ti–4.35La, which exhibited remarkable efficiency for grain refinement from 1.46 mm into ~ 0.1 mm (with 0.2 wt pct of the refiner), increasing both tensile strength, yield strength, elongation and hardness from 154.3 MPa, 64.5 MP, 5.83 pct, and 54.8 HV to 178.3 MPa (an enhancement of 15.6 pct), 77.5 MPa(an enhancement of 20.2 pct), 12.02 pct (an enhancement of 106.0 pct), and 58.4 HV (an increase of 6.6 pct), respectively. The in situ formation of the Ti<sub>2</sub>Al<sub>20</sub>La phase served as the nucleus for <i>α</i>-Al during solidification. The segregation of trace Si and La atoms at the interface indicates their chemical affinity with a relatively lower energy configuration, which is consistent with the first-principles calculations. The results of this study offer an innovative approach for attaining considerable grain refinement in Al–7Si alloys by constructing rare-earth grain refiners.</p>","PeriodicalId":18504,"journal":{"name":"Metallurgical and Materials Transactions A","volume":"18 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Refinement Mechanism of the Hypoeutectic Al–7Si Alloy by Adding a Novel La-Rich Rare-Earth Grain Refiner\",\"authors\":\"Wanwu Ding, Mei Xu, Lumin Gou, Lingxia Li, Juan Ma, Jiazhi An, Xuefeng Lu, Xiaochun Liu, Xiaochun Li\",\"doi\":\"10.1007/s11661-024-07510-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Refining the grain size of the as-casted hypoeutectic Al–Si alloys is an established technique for improving their mechanical properties. This work is based on the development of a novel La-riched grain refiner, <i>i.e.</i>, Al–3Ti–4.35La, which exhibited remarkable efficiency for grain refinement from 1.46 mm into ~ 0.1 mm (with 0.2 wt pct of the refiner), increasing both tensile strength, yield strength, elongation and hardness from 154.3 MPa, 64.5 MP, 5.83 pct, and 54.8 HV to 178.3 MPa (an enhancement of 15.6 pct), 77.5 MPa(an enhancement of 20.2 pct), 12.02 pct (an enhancement of 106.0 pct), and 58.4 HV (an increase of 6.6 pct), respectively. The in situ formation of the Ti<sub>2</sub>Al<sub>20</sub>La phase served as the nucleus for <i>α</i>-Al during solidification. The segregation of trace Si and La atoms at the interface indicates their chemical affinity with a relatively lower energy configuration, which is consistent with the first-principles calculations. The results of this study offer an innovative approach for attaining considerable grain refinement in Al–7Si alloys by constructing rare-earth grain refiners.</p>\",\"PeriodicalId\":18504,\"journal\":{\"name\":\"Metallurgical and Materials Transactions A\",\"volume\":\"18 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-07-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Metallurgical and Materials Transactions A\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1007/s11661-024-07510-9\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Metallurgical and Materials Transactions A","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1007/s11661-024-07510-9","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Refinement Mechanism of the Hypoeutectic Al–7Si Alloy by Adding a Novel La-Rich Rare-Earth Grain Refiner
Refining the grain size of the as-casted hypoeutectic Al–Si alloys is an established technique for improving their mechanical properties. This work is based on the development of a novel La-riched grain refiner, i.e., Al–3Ti–4.35La, which exhibited remarkable efficiency for grain refinement from 1.46 mm into ~ 0.1 mm (with 0.2 wt pct of the refiner), increasing both tensile strength, yield strength, elongation and hardness from 154.3 MPa, 64.5 MP, 5.83 pct, and 54.8 HV to 178.3 MPa (an enhancement of 15.6 pct), 77.5 MPa(an enhancement of 20.2 pct), 12.02 pct (an enhancement of 106.0 pct), and 58.4 HV (an increase of 6.6 pct), respectively. The in situ formation of the Ti2Al20La phase served as the nucleus for α-Al during solidification. The segregation of trace Si and La atoms at the interface indicates their chemical affinity with a relatively lower energy configuration, which is consistent with the first-principles calculations. The results of this study offer an innovative approach for attaining considerable grain refinement in Al–7Si alloys by constructing rare-earth grain refiners.