{"title":"烯烃和炔烃与基于噻蒽骨架的新型二茂铁锍盐的二茂铁化反应","authors":"","doi":"10.1016/j.tetlet.2024.155165","DOIUrl":null,"url":null,"abstract":"<div><p>A novel electrophilic ferrocenylating reagent, thianthrene-based S-ferrocenyl sulfonium salt, has been be synthesized in one pot from ferrocenyl lithium. This bench-stable ferrocenylating reagent shows excellent thermos-stability and reactivity, and has been demonstrated to allow access to complex ferrocene architectures from various terminal alkenes or alkynes.</p></div>","PeriodicalId":438,"journal":{"name":"Tetrahedron Letters","volume":null,"pages":null},"PeriodicalIF":1.5000,"publicationDate":"2024-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The ferrocenylation reaction of olefins and alkynes with a novel ferrocenyl sulfonium salt based on thianthrene skeleton\",\"authors\":\"\",\"doi\":\"10.1016/j.tetlet.2024.155165\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A novel electrophilic ferrocenylating reagent, thianthrene-based S-ferrocenyl sulfonium salt, has been be synthesized in one pot from ferrocenyl lithium. This bench-stable ferrocenylating reagent shows excellent thermos-stability and reactivity, and has been demonstrated to allow access to complex ferrocene architectures from various terminal alkenes or alkynes.</p></div>\",\"PeriodicalId\":438,\"journal\":{\"name\":\"Tetrahedron Letters\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2024-07-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Tetrahedron Letters\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0040403924002600\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Tetrahedron Letters","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0040403924002600","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
The ferrocenylation reaction of olefins and alkynes with a novel ferrocenyl sulfonium salt based on thianthrene skeleton
A novel electrophilic ferrocenylating reagent, thianthrene-based S-ferrocenyl sulfonium salt, has been be synthesized in one pot from ferrocenyl lithium. This bench-stable ferrocenylating reagent shows excellent thermos-stability and reactivity, and has been demonstrated to allow access to complex ferrocene architectures from various terminal alkenes or alkynes.
期刊介绍:
Tetrahedron Letters provides maximum dissemination of outstanding developments in organic chemistry. The journal is published weekly and covers developments in techniques, structures, methods and conclusions in experimental and theoretical organic chemistry. Rapid publication of timely and significant research results enables researchers from all over the world to transmit quickly their new contributions to large, international audiences.