{"title":"紫水晶中 Fe2+ 杂质离子地面电子态的 EPR 光谱分析","authors":"V. F. Tarasov, R. B. Zaripov","doi":"10.1007/s00723-024-01683-7","DOIUrl":null,"url":null,"abstract":"<div><p>Properties of two lowest electron levels of the Fe<sup>2+</sup> impurity ion in a natural amethyst are studied by continuous wave electron paramagnetic resonance spectroscopy in the Q-band. It is established that the these levels present quasi-doublet <span>\\(\\left| { \\pm 2} \\right\\rangle\\)</span>with zero-field splitting of 30.9 ± 0.2 GHz. Orientation of principal magnetic axes and value of <i>g</i>-factor of this paramagnetic center are determined.</p></div>","PeriodicalId":469,"journal":{"name":"Applied Magnetic Resonance","volume":"55 9","pages":"961 - 967"},"PeriodicalIF":1.1000,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"EPR Spectroscopy of the Ground Electron State of the Fe2+ Impurity Ion in Amethyst\",\"authors\":\"V. F. Tarasov, R. B. Zaripov\",\"doi\":\"10.1007/s00723-024-01683-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Properties of two lowest electron levels of the Fe<sup>2+</sup> impurity ion in a natural amethyst are studied by continuous wave electron paramagnetic resonance spectroscopy in the Q-band. It is established that the these levels present quasi-doublet <span>\\\\(\\\\left| { \\\\pm 2} \\\\right\\\\rangle\\\\)</span>with zero-field splitting of 30.9 ± 0.2 GHz. Orientation of principal magnetic axes and value of <i>g</i>-factor of this paramagnetic center are determined.</p></div>\",\"PeriodicalId\":469,\"journal\":{\"name\":\"Applied Magnetic Resonance\",\"volume\":\"55 9\",\"pages\":\"961 - 967\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2024-07-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Magnetic Resonance\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s00723-024-01683-7\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Magnetic Resonance","FirstCategoryId":"101","ListUrlMain":"https://link.springer.com/article/10.1007/s00723-024-01683-7","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL","Score":null,"Total":0}
EPR Spectroscopy of the Ground Electron State of the Fe2+ Impurity Ion in Amethyst
Properties of two lowest electron levels of the Fe2+ impurity ion in a natural amethyst are studied by continuous wave electron paramagnetic resonance spectroscopy in the Q-band. It is established that the these levels present quasi-doublet \(\left| { \pm 2} \right\rangle\)with zero-field splitting of 30.9 ± 0.2 GHz. Orientation of principal magnetic axes and value of g-factor of this paramagnetic center are determined.
期刊介绍：
Applied Magnetic Resonance provides an international forum for the application of magnetic resonance in physics, chemistry, biology, medicine, geochemistry, ecology, engineering, and related fields.
The contents include articles with a strong emphasis on new applications, and on new experimental methods. Additional features include book reviews and Letters to the Editor.
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