双环[3.1.1]庚烷合成的最新进展

Synthesis Pub Date : 2024-07-16 DOI:10.1055/a-2367-2244
Jianyang Dong, Huijuan Liao, Dong Xue
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引用次数: 0

摘要

在过去三年中,双环[3.1.1]庚烷及其结构类似物已成为有用的元取代(杂)烷生物异养生物。为了满足对双环[3.1.1]庚烷日益增长的需求,化学家们开发了大量新的合成方法。在本综述中,我们将从范围和机理两方面评估其合成和功能化的研究进展。此外,我们还讨论了确定新型反应歧管以获得新型官能化双环[3.1.1]庚烷所面临的挑战和前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Recent Advances in the Synthesis of Bicyclo[3.1.1]heptanes
In the past three years, bicyclo[3.1.1]heptanes and their structural analogues have emerged as useful bioisosteres of meta-substituted (hetero)arenes. To meet increasing demand for bicyclo[3.1.1]heptanes, chemists have developed a plethora of novel methods for their synthesis. In this review, we assess research progress on their synthesis and functionalization, considering both scope and mechanism. In addition, we discuss the challenges posed by and outlook for the identification of novel reaction manifolds to access novel functionalized bicyclo[3.1.1]heptanes.
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