In(III) 离子电还原的电化学测量;混合吸附层 ACT-CTAB 和 ACT-SDS 的影响

A. Nosal-Wiercińska, M. Martyna, Sultan Yagmur-Kabas
{"title":"In(III) 离子电还原的电化学测量;混合吸附层 ACT-CTAB 和 ACT-SDS 的影响","authors":"A. Nosal-Wiercińska, M. Martyna, Sultan Yagmur-Kabas","doi":"10.1149/1945-7111/ad6191","DOIUrl":null,"url":null,"abstract":"\n Using voltammetric and impedance methods, the effects of mixed adsorption layers ACT-CTAB and ACT-SDS on the kinetics and mechanism of In(III) ions electroreduction were investigated. Acetazolamide (ACT) was shown to catalyse the course of the electrode reaction (according to the cap-pair rule). The multi-step nature of the In(III) ions electroreduction process in each of the systems studied in the chemical step of formation of the active In(III) - ACT complexes in the adsorption layer playing an important role is demonstrated. The presence of the cationic surfactant CTAB increases the dynamics of acceleration of the In(III) ion electroreduction process by ACT, while the presence of the anionic surfactant SDS inhibits this reaction.","PeriodicalId":509718,"journal":{"name":"Journal of The Electrochemical Society","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Electrochemical Measurements of the In(III) Ions Electroreduction; the Influence of Mixed Adsorption Layers ACT-CTAB and ACT-SDS\",\"authors\":\"A. Nosal-Wiercińska, M. Martyna, Sultan Yagmur-Kabas\",\"doi\":\"10.1149/1945-7111/ad6191\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"\\n Using voltammetric and impedance methods, the effects of mixed adsorption layers ACT-CTAB and ACT-SDS on the kinetics and mechanism of In(III) ions electroreduction were investigated. Acetazolamide (ACT) was shown to catalyse the course of the electrode reaction (according to the cap-pair rule). The multi-step nature of the In(III) ions electroreduction process in each of the systems studied in the chemical step of formation of the active In(III) - ACT complexes in the adsorption layer playing an important role is demonstrated. The presence of the cationic surfactant CTAB increases the dynamics of acceleration of the In(III) ion electroreduction process by ACT, while the presence of the anionic surfactant SDS inhibits this reaction.\",\"PeriodicalId\":509718,\"journal\":{\"name\":\"Journal of The Electrochemical Society\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-07-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Electrochemical Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1149/1945-7111/ad6191\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Electrochemical Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1149/1945-7111/ad6191","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

利用伏安法和阻抗法研究了 ACT-CTAB 和 ACT-SDS 混合吸附层对 In(III) 离子电还原动力学和机理的影响。研究表明,乙酰唑胺(ACT)催化了电极反应过程(根据盖对规则)。在所研究的每个体系中,In(III) 离子电还原过程都具有多步骤性质,其中在吸附层中形成活性 In(III) - ACT 复合物的化学步骤发挥了重要作用。阳离子表面活性剂 CTAB 的存在增加了 ACT 加速 In(III) 离子电还原过程的动力,而阴离子表面活性剂 SDS 的存在则抑制了这一反应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Electrochemical Measurements of the In(III) Ions Electroreduction; the Influence of Mixed Adsorption Layers ACT-CTAB and ACT-SDS
Using voltammetric and impedance methods, the effects of mixed adsorption layers ACT-CTAB and ACT-SDS on the kinetics and mechanism of In(III) ions electroreduction were investigated. Acetazolamide (ACT) was shown to catalyse the course of the electrode reaction (according to the cap-pair rule). The multi-step nature of the In(III) ions electroreduction process in each of the systems studied in the chemical step of formation of the active In(III) - ACT complexes in the adsorption layer playing an important role is demonstrated. The presence of the cationic surfactant CTAB increases the dynamics of acceleration of the In(III) ion electroreduction process by ACT, while the presence of the anionic surfactant SDS inhibits this reaction.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
Harnessing Cold Sintering to Fabricate Composite Polymer Electrolytes - A Paradigm Shift in Organic-Inorganic Material Assembly Investigating Plastic Deformation Between Silicon and Solid Electrolyte in All-Solid-State Batteries Using Operando X-ray Tomography Mild and Fast Chemical Presodiation of Na0.44MnO2 Facile Synthesis of U2Ti Intermetallic by Direct Electrochemical Reduction of UO2-TiO2 Composite in LiCl-Li2O Melt Binderless Electrodeposited NiCo2S4-MWCNT as a Potential Anode Material for Sodium-Ion Batteries
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1