天然气燃烧影响土壤中的重金属污染:尼日利亚巴耶尔萨州 Obunagha 的污染指数评估

Wurutuawei T. Silver, Erepamowei Young, Ajoko T. Imomotimi, Woyengidoubara W. T. Angaye, Christopher Unyime Ebong
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摘要

天然气燃烧是指在石油勘探和开采活动中利用燃烧烟囱有控制地燃烧天然气。在尼日利亚,天然气燃烧活动频繁,主要发生在尼日尔三角洲地区。本研究的目的是利用污染指数(如污染因子、地质累积指数和污染负荷指数)调查受天然气燃烧影响的土壤中重金属污染的生物利用率和浓度。使用土壤钻在距离燃放点 200 米、500 米、1000 米、2000 米和 3000 米处的 0-15 厘米深处采集土壤样本。采用火焰原子吸收光谱法评估了土壤中以下重金属的含量:镉、铬、镍、锌、铜和锰。研究结果表明,在土壤中测试的金属中,铁的生物利用率最高(90%),而铬的生物利用率最低(45%)。金属的生物利用率按照铁>锰>铜>镉>镍>锌>铬的顺序依次降低。地质累积指数显示,土壤在所有距离上基本未受到锌和铜的污染,在 1000 米和 2000 米处受到镉和镍的中度污染,在 200 米处受到镉的严重污染。污染物负荷指数(PLI)较高,但随着距燃烧点距离的增加而降低(1.37-0.49),表明研究区域受到污染。总之,研究的总体结果表明,由于附近的天然气燃烧,土壤受到了重金属(尤其是镉)的污染。因此,必须对该地区进行适当的监测和管理,以防止未来土壤受重金属污染达到危害人类健康的程度。
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Heavy Metal Pollution in Gas Flare-Impacted Soils: An Assessment Using Pollution Indices in Obunagha, Bayelsa State, Nigeria
Gas flaring is the controlled burning of natural gas which occurs as a result of the activities of oil exploration and exploitation using flare stacks. In Nigeria, gas flaring activities is high and it mainly takes place in the Niger Delta region. The aim of this study was to investigate the bioavailability and concentration of heavy metals pollution of gas flare-impacted soils using pollution indices such as contamination factor, geo-accumulation index and pollution load index. Soil samples were collected with soil auger at depths of 0-15 cm from distances of 200 m, 500 m, 1000 m, 2000 m, and 3000 m away from the flaring point. Flame atomic absorption spectrometry was used to assess the presence of the following heavy metals in the soils: cadmium, chromium, nickel, zinc, copper, and manganese. The findings revealed that Fe (90% bioavailability) had the highest bioavailability among the metals tested in the soils, while Cr (45%) had the lowest. The metals bioavailability decreased in the order of Fe>Mn>Cu>Cd>Ni>Zn>Cr. The geo-accumulation index revealed that the soils were practically uncontaminated by Zn and Cu at all distances, moderately polluted by Cd and Ni at 1000 m and 2000 m and strongly polluted with Cd at a distance of 200 m. The Contamination factor results were consistent with the geo-accumulation index results. The pollutant load index (PLI) was found to be high but decreasing (1.37-0.49) as the distance from the flare point increased, indicating that the research region was polluted. In conclusion, the study's overall findings suggested that the soils were contaminated with heavy metals (particularly Cd) as a result of nearby gas flaring. As a result, the area must be appropriately monitored and managed to prevent future soil contamination by heavy metals to a level that is hazardous to human health.
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