{"title":"二羰基-1κ2 C-μ-chlorido-2:3κ2 Cl:Cl-pentachlorido-2κ2 Cl,3κ3 Cl-[1(η6)-toluene]digallium(III)ruthenium(I)(Ru-Ga)","authors":"Danielle Smith , George N. Harakas","doi":"10.1107/S2414314624006576","DOIUrl":null,"url":null,"abstract":"<div><p>The title compound is a ruthenium–gallium metal cluster. The ruthenium and gallium have a direct metal–metal bond with a length of 2.4575 (2) Å.</p></div><div><p>The title compound, [RuGa<sub>2</sub>Cl<sub>6</sub>(C<sub>7</sub>H<sub>8</sub>)(CO)<sub>2</sub>] or [(CO)<sub>2</sub>(GaCl<sub>2</sub>)(η<sup>6</sup>-toluene)Ru]<sup>+</sup>[GaCl<sub>4</sub>]<sup>−</sup>, was isolated from the reaction of Ga<sub>2</sub>Cl<sub>4</sub> with diphenylsilanediol in toluene, followed by the addition of Ru<sub>3</sub>(CO)<sub>12</sub>. The compound contains a ruthenium–gallium metal–metal bond with a length of 2.4575 (2) Å.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (242KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></p></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 7","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Dicarbonyl-1κ2C-μ-chlorido-2:3κ2Cl:Cl-pentachlorido-2κ2Cl,3κ3Cl-[1(η6)-toluene]digallium(III)ruthenium(I)(Ru—Ga)\",\"authors\":\"Danielle Smith , George N. Harakas\",\"doi\":\"10.1107/S2414314624006576\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The title compound is a ruthenium–gallium metal cluster. The ruthenium and gallium have a direct metal–metal bond with a length of 2.4575 (2) Å.</p></div><div><p>The title compound, [RuGa<sub>2</sub>Cl<sub>6</sub>(C<sub>7</sub>H<sub>8</sub>)(CO)<sub>2</sub>] or [(CO)<sub>2</sub>(GaCl<sub>2</sub>)(η<sup>6</sup>-toluene)Ru]<sup>+</sup>[GaCl<sub>4</sub>]<sup>−</sup>, was isolated from the reaction of Ga<sub>2</sub>Cl<sub>4</sub> with diphenylsilanediol in toluene, followed by the addition of Ru<sub>3</sub>(CO)<sub>12</sub>. The compound contains a ruthenium–gallium metal–metal bond with a length of 2.4575 (2) Å.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (242KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></p></div>\",\"PeriodicalId\":94324,\"journal\":{\"name\":\"IUCrData\",\"volume\":\"9 7\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2414314624000646\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/7/9 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314624000646","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/7/9 0:00:00","PubModel":"Epub","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
标题化合物[RuGa2Cl6(C7H8)(CO)2]或[(CO)2(GaCl2)(η6-甲苯)Ru]+[GaCl4]-是从 Ga2Cl4 与二苯基硅二醇在甲苯中的反应中分离出来的，随后加入了 Ru3(CO)12。该化合物含有一个长度为 2.4575 (2) Å 的钌镓金属-金属键。
The title compound is a ruthenium–gallium metal cluster. The ruthenium and gallium have a direct metal–metal bond with a length of 2.4575 (2) Å.
The title compound, [RuGa2Cl6(C7H8)(CO)2] or [(CO)2(GaCl2)(η6-toluene)Ru]+[GaCl4]−, was isolated from the reaction of Ga2Cl4 with diphenylsilanediol in toluene, followed by the addition of Ru3(CO)12. The compound contains a ruthenium–gallium metal–metal bond with a length of 2.4575 (2) Å.
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