微气泡剂量在细颗粒联合微气浮中的作用

Nickolay Rulyov
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摘要

小颗粒浮选是矿物原料加工业面临的全球性挑战之一。由于传统浮选机产生的粗气泡捕集效果不佳,大量有色金属和稀有金属以 15 微米以下矿物颗粒的形式在浮选尾矿中流失。近年来开发的组合微浮选法使用了传统的粗气泡(CB)和水包气微分散独立发生器产生的微气泡(MB),后者可作为浮选载体。根据 MB 剂量的不同,其应用效果可能是积极的,也可能是消极的。通过对颗粒转移到粗气泡表面并进一步进入泡沫层的各种机制进行理论分析,得出了最佳甲基溴剂量公式 f=dd/2dprp,其中 dd 为甲基溴大小;dp 和 rp 分别为颗粒大小和密度。在 Atalaya 矿业公司(西班牙)和 Chaarat Kapan 公司(亚美尼亚)选矿厂对铜矿浮选 尾矿进行的实验表明,除了 1-3 毫升/克范围内的最佳甲基溴剂量外,还有 10-20 毫升/克范围内的另一种最佳甲基溴剂量,与参考试验(f = 0)相比,铜回收率提高了几个百分点。在最佳甲基溴剂量之间的区域,铜回收率最低,比参照试验的值低几个百分点。
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The role of microbubble dose in combined microflotation of fine particles
Flotation of small particles is one of the global challenges facing the mineral raw materials processing industry. Large amounts of non-ferrous and rare metals are lost in the flotation tailings in the form of mineral particles below 15 µm in size as a result of the low effectiveness of their capture by coarse bubbles generated in conventional flotation machines. The method of combined microflotation, developed in recent years, uses conventional coarse bubbles (CB) and microbubbles (MB) produced in the stand-alone generator of air-in-water microdispersion, which serves as the flotation carriers. Depending on the MB dose, the effect of their application may be positive or negative. The theoretical analysis of various mechanisms of particle transfer onto the surface of coarse bubbles and further into the froth layer allowed to obtain the formula for the optimal MB dose f=dd/2dprp, where dd is MB size; dp and rp respectively are the size and the density of particles. Experiments performed on the copper ore flotation tailings at the Atalaya Mining (Spain) and Chaarat Kapan (Armenia) concentrators showed that, besides the optimal MB dose in the range of 1-3 ml/g, there is another optimal MB dose in the range of 10-20 ml/g, where the copper recovery increases by several percent compared to the reference test (f = 0). The deep minimum in copper recovery is observed in the area between the optimal MB doses, which is by several percent lower than the value in the reference test.
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