{"title":"对 MillerCoors 诉 Anheuser-Busch 案索赔的碳同位素评估","authors":"Gwyneth W. Gordon","doi":"10.1016/j.forc.2024.100598","DOIUrl":null,"url":null,"abstract":"<div><p>MillerCoors (MC) sued Anheuser-Busch (AB) over a 2019 advertising campaign emphasizing that Miller Lite and Coors Light beers are made with corn syrup. Because plants using the C4 photosynthetic pathway (corn, sugar cane, millet) are isotopically enriched in <sup>13</sup>C, relative to <sup>12</sup>C, in plants that use the C3 pathway (rice, barley, rye, wheat), carbon isotopes can provide relevant evidence. The plaintiff, MC, asserted 1) there is no corn syrup in the final product of Miller Lite or Coors Light; 2) they never use high fructose corn syrup (HFCS); 3) AB uses corn syrup as a fermentation aid in other products; and 4) AB adds HFCS to other product lines. I measured <em>δ</em> <sup>13</sup>C<sub>VPDB</sub> values for 27 beers, including the eight best-selling U.S. beers covering > 50% of the U.S. market. Miller Lite (−24.6 ‰) and Coors Light (−24.5 ‰) had 0–15% carbon from C4 sources, while Bud Light (−27.3 ‰), an AB product, had little to no C4 carbon. However, other AB products use more C4 carbon sources, including Bud Light Platinum (−22.0 ‰, 27 ±5% C4), Natural Light (−22.1 ‰, 26 ±5% C4), Category 5 Malt Hurricane (−21.1 ‰, 33 ±5% C4), Rolling Rock Extra Pale (−20.7 ‰, 37 ±5% C4), and Lime-A-Rita (−11.9 ‰, 98<!--> <!-->±4% C4). Corn syrup and HFCS were isotopically indistinguishable. This study supports claim 3, but cannot address claims 1, 2, and 4, highlighting both the utility and limitations of <em>δ</em> <sup>13</sup>C measurements in ingredient identification in a civil case.</p></div>","PeriodicalId":324,"journal":{"name":"Forensic Chemistry","volume":"40 ","pages":"Article 100598"},"PeriodicalIF":2.6000,"publicationDate":"2024-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Carbon isotope evaluation of the claims in MillerCoors vs Anheuser-Busch\",\"authors\":\"Gwyneth W. Gordon\",\"doi\":\"10.1016/j.forc.2024.100598\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>MillerCoors (MC) sued Anheuser-Busch (AB) over a 2019 advertising campaign emphasizing that Miller Lite and Coors Light beers are made with corn syrup. Because plants using the C4 photosynthetic pathway (corn, sugar cane, millet) are isotopically enriched in <sup>13</sup>C, relative to <sup>12</sup>C, in plants that use the C3 pathway (rice, barley, rye, wheat), carbon isotopes can provide relevant evidence. The plaintiff, MC, asserted 1) there is no corn syrup in the final product of Miller Lite or Coors Light; 2) they never use high fructose corn syrup (HFCS); 3) AB uses corn syrup as a fermentation aid in other products; and 4) AB adds HFCS to other product lines. I measured <em>δ</em> <sup>13</sup>C<sub>VPDB</sub> values for 27 beers, including the eight best-selling U.S. beers covering > 50% of the U.S. market. Miller Lite (−24.6 ‰) and Coors Light (−24.5 ‰) had 0–15% carbon from C4 sources, while Bud Light (−27.3 ‰), an AB product, had little to no C4 carbon. However, other AB products use more C4 carbon sources, including Bud Light Platinum (−22.0 ‰, 27 ±5% C4), Natural Light (−22.1 ‰, 26 ±5% C4), Category 5 Malt Hurricane (−21.1 ‰, 33 ±5% C4), Rolling Rock Extra Pale (−20.7 ‰, 37 ±5% C4), and Lime-A-Rita (−11.9 ‰, 98<!--> <!-->±4% C4). Corn syrup and HFCS were isotopically indistinguishable. This study supports claim 3, but cannot address claims 1, 2, and 4, highlighting both the utility and limitations of <em>δ</em> <sup>13</sup>C measurements in ingredient identification in a civil case.</p></div>\",\"PeriodicalId\":324,\"journal\":{\"name\":\"Forensic Chemistry\",\"volume\":\"40 \",\"pages\":\"Article 100598\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-07-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Forensic Chemistry\",\"FirstCategoryId\":\"3\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S246817092400050X\",\"RegionNum\":3,\"RegionCategory\":\"医学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Forensic Chemistry","FirstCategoryId":"3","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S246817092400050X","RegionNum":3,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Carbon isotope evaluation of the claims in MillerCoors vs Anheuser-Busch
MillerCoors (MC) sued Anheuser-Busch (AB) over a 2019 advertising campaign emphasizing that Miller Lite and Coors Light beers are made with corn syrup. Because plants using the C4 photosynthetic pathway (corn, sugar cane, millet) are isotopically enriched in 13C, relative to 12C, in plants that use the C3 pathway (rice, barley, rye, wheat), carbon isotopes can provide relevant evidence. The plaintiff, MC, asserted 1) there is no corn syrup in the final product of Miller Lite or Coors Light; 2) they never use high fructose corn syrup (HFCS); 3) AB uses corn syrup as a fermentation aid in other products; and 4) AB adds HFCS to other product lines. I measured δ13CVPDB values for 27 beers, including the eight best-selling U.S. beers covering > 50% of the U.S. market. Miller Lite (−24.6 ‰) and Coors Light (−24.5 ‰) had 0–15% carbon from C4 sources, while Bud Light (−27.3 ‰), an AB product, had little to no C4 carbon. However, other AB products use more C4 carbon sources, including Bud Light Platinum (−22.0 ‰, 27 ±5% C4), Natural Light (−22.1 ‰, 26 ±5% C4), Category 5 Malt Hurricane (−21.1 ‰, 33 ±5% C4), Rolling Rock Extra Pale (−20.7 ‰, 37 ±5% C4), and Lime-A-Rita (−11.9 ‰, 98 ±4% C4). Corn syrup and HFCS were isotopically indistinguishable. This study supports claim 3, but cannot address claims 1, 2, and 4, highlighting both the utility and limitations of δ13C measurements in ingredient identification in a civil case.
期刊介绍:
Forensic Chemistry publishes high quality manuscripts focusing on the theory, research and application of any chemical science to forensic analysis. The scope of the journal includes fundamental advancements that result in a better understanding of the evidentiary significance derived from the physical and chemical analysis of materials. The scope of Forensic Chemistry will also include the application and or development of any molecular and atomic spectrochemical technique, electrochemical techniques, sensors, surface characterization techniques, mass spectrometry, nuclear magnetic resonance, chemometrics and statistics, and separation sciences (e.g. chromatography) that provide insight into the forensic analysis of materials. Evidential topics of interest to the journal include, but are not limited to, fingerprint analysis, drug analysis, ignitable liquid residue analysis, explosives detection and analysis, the characterization and comparison of trace evidence (glass, fibers, paints and polymers, tapes, soils and other materials), ink and paper analysis, gunshot residue analysis, synthetic pathways for drugs, toxicology and the analysis and chemistry associated with the components of fingermarks. The journal is particularly interested in receiving manuscripts that report advances in the forensic interpretation of chemical evidence. Technology Readiness Level: When submitting an article to Forensic Chemistry, all authors will be asked to self-assign a Technology Readiness Level (TRL) to their article. The purpose of the TRL system is to help readers understand the level of maturity of an idea or method, to help track the evolution of readiness of a given technique or method, and to help filter published articles by the expected ease of implementation in an operation setting within a crime lab.