Fe3O4/PANI/CuI 作为用于 A3 偶联的可持续异质纳米催化剂。

IF 4.6 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY Nanoscale Advances Pub Date : 2024-07-22 DOI:10.1039/d4na00448e
Nisha Kharb, Sahil Kohli, Snigdha Singh, Neera Sharma, Ramesh Chandra
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引用次数: 0

摘要

将制备的碘化铜纳米颗粒浸渍在聚苯胺功能化的铁氧体纳米颗粒上,得到了一种磁性可回收的异质纳米复合材料。对制备的纳米复合材料在温和条件下通过 A3 偶联合成丙炔胺衍生物的催化活性进行了评估。XRD、傅立叶变换红外光谱、EDAX、XPS、TEM 和 FESEM 等技术用于表征本研究中开发的有效而独特的异质 Fe3O4/PANI/CuI 纳米复合材料。本研究具有几个优点,包括反应时间短、无溶剂条件、产品收率高、化学基质值理想、可重复使用长达七个周期以及磁性可回收性。
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Fe3O4/PANI/CuI as sustainable heterogenous nanocatalyst for A3 coupling.
The prepared copper iodide nanoparticles were impregnated on the support of ferrite nanoparticles functionalized with polyaniline, resulting in a magnetically recoverable heterogeneous nanocomposite. The catalytic activity of the prepared nanocomposite was evaluated for the synthesis of propargylamine derivatives via A3 coupling under mild conditions. Techniques such as XRD, FTIR, EDAX, XPS, TEM, and FESEM were used to characterize the effective and unique heterogeneous Fe3O4/PANI/CuI nanocomposite developed in this work. This current study has several advantages, including a short reaction time, solvent-free conditions, high product yield, ideal chemistry matrices values, reusability for up to seven cycles, and magnetic retrievability.
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来源期刊
Nanoscale Advances
Nanoscale Advances Multiple-
CiteScore
8.00
自引率
2.10%
发文量
461
审稿时长
9 weeks
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