含氧化锌的丙烯腈橡胶作为安全产品的评估

Doaa E. El Nashar, Soheir Y. Tawfik, Fahima M. Helaly, Aman I. Khalaf, Abdelmohsen M. Soliman
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摘要

本研究的目标是找到在流变学、物理机械和最低毒性特性方面具有最佳抗菌性能的理想配方,从而生产出安全橡胶,用于儿童玩具和其他工业产品。为了实现这一目标,我们制备了一些配方,这些配方含有作为硫化过程活化剂的氧化锌以及抗菌剂,浓度范围为 1.5 至 40 phr,并含有 40 phr 的不同填料。对制备的复合橡胶样品的流变特性进行了评估,并计算了硫化率。总体流变测试结果表明,最小扭矩和最大扭矩提高了,焦烧和最佳硫化时间缩短了。根据估计的硫化时间对混合丁腈橡胶进行硫化。结果表明,含有不同数量氧化锌和 40 phr 滑石粉的丁腈橡胶硫化胶具有最佳的物理机械性能。此外,扫描电子显微照片还显示出丁腈橡胶成分的表面均匀性和良好的分散性。对正常视网膜细胞系进行的细胞毒性测试表明,所研究的硫化胶没有产生细胞毒性效应,从而评估了它们的安全性。这些发现为用于儿童玩具和其他安全产品的抗菌丁腈橡胶硫化胶提供了有用的信息。使用的抗菌剂是氧化锌。ZnO 纳米粒子和其他成分在普通橡胶混合器上与丁腈橡胶混合。测试了丁腈橡胶的流变学、物理机械性能和抗菌活性。产品具有更好的机械和抗菌安全性能。
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Evaluation of acrylonitrile rubber containing zinc oxide as safety products
The goal of this research is to find the ideal formulation with the best antimicrobial performance in terms of rheological, physicomechanical, and lowest toxic properties to produce safety rubber for the children toy's and other industrial products. In order to accomplish this, a number of formulations containing ZnO as activator for vulcanization process as well as an antimicrobial agent at concentrations ranging from 1.5 to 40 phr in the presence of 40 phr of different fillers were prepared. The rheological characteristics of prepared compounded rubber samples were assessed and the cure rate was calculated. The overall rheological test results indicate a raise in minimum and maximum torque along with a fall in scorch and optimum cure time. The compounded NBR was vulcanized as estimated curing time. The results illustrated that the NBR vulcanizates containing various amounts of ZnO and 40 phr talc have the best physicomechanical properties. Also, the scanning electron micrographs indicated surface homogeneity and good dispersion of the NBR components. The cytotoxicity test of the investigated vulcanizates on normal retina cell line gave no cytotoxic effect which assessed their safety. These findings offer useful information for antimicrobial NBR vulcanizates for kid's toys and other safety products.Highlights Synthesis of antimicrobial NBR rubber vulcanizates for safety applications. The antimicrobial agent used was ZnO. ZnO nanoparticles and other ingredients were incorporated with NBR on the ordinary rubber mixer. Rheological, physicomechanical properties and antimicrobial activity of NBR rubber were tested. The products have better mechanical and antimicrobial safety properties.
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