大型锡(IV)氧化物团簇的结构

Ulrich Schubert
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引用次数: 0

摘要

文章对核度≥6 的锡氧化簇结构进行了回顾和分类,并将其与其他第 4 组和第 14 组金属的氧化簇进行了比较。通过比较不同的簇类型和识别较小的构件,得出了簇核的基本构造原理。比较还显示了稳定簇核的配体与桥接氧原子之间的相互作用对不同簇类型的影响。
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Structures of Large Tin(IV) Oxo Clusters
The article reviews and categorizes the structures of tin oxo clusters with nuclearities ≥6 and compares them with oxo clusters of the other group 4 and 14 metals. Basic construction principles of the cluster core are worked out by comparing the different cluster types and by identifying smaller building blocks. The comparison also shows how the different cluster types are influenced by the interplay between the ligands which stabilize the cluster core and the bridging oxygen atoms.
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