多烯和烯烃在七元环丙氨酰的 [4 + 1] 环加成反应

Michael Stephen Hill, Han-Ying Liu, Mary F. Mahon
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引用次数: 0

摘要

我们研究了[{SiNDipp}AlK]2 对各种 1,3-二烯分子(包括 2,3-二甲基丁二烯、环辛四烯、蒽和四蒽)的反应性,[{SiNDipp}AlK]2 包含一个形式上为阴离子的 Al(I)中心。在每种情况下,铝酰衍生物都会通过铝(I)中心发生氧化加成,从而提供相应的铝环戊烯钾、铝环丙烯钾或铝降冰片二烯钾的 [4 + 1] 环加成产物。
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Polyene and Arene [4 + 1] Cycloaddition at a Seven‐Membered Cyclic Alumanyl
The reactivity of [{SiNDipp}AlK]2, which comprises a formally anionic Al(I) centre, has been examined towards a variety of 1,3‐dienic molecules, including 2,3‐dimethylbutadiene, cyclooctatetraene, anthracene and tetracene. In each case, the alumanyl derivative experiences oxidative addition across the Al(I) centre to provide the corresponding potassium aluminacyclopentene, aluminacyclopropene or aluminanorbornadiene products of [4 + 1] cycloaddition.
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