N. G. Bykova, A. L. Kusov, P. V. Kozlov, G. Ya. Gerasimov, V. Yu. Levashov, I. E. Zabelinsky
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Spectral Model for Calculation of Radiation Characteristics of a Shock-Heated Gas
Abstract
An extended version of the previously developed computational procedure SPECTRUM is presented, which allows us to calculate the radiation characteristics of a shock-heated gas, taking into account the decrease in the radiation intensity in an absorbing medium. The procedure is based on a line-by-line calculation of the emission and absorption spectra of the atoms and molecules that make up the studied gas mixture. When calculating the emission spectra of atoms and molecules, the values of spectroscopic constants are taken from well-known databases. The results of calculating the time-integrated spectral characteristics of shock-heated air are compared with the available experimental data obtained in the ultraviolet, visible, and infrared regions of the spectrum.
期刊介绍:
Russian Journal of Physical Chemistry B: Focus on Physics is a journal that publishes studies in the following areas: elementary physical and chemical processes; structure of chemical compounds, reactivity, effect of external field and environment on chemical transformations; molecular dynamics and molecular organization; dynamics and kinetics of photoand radiation-induced processes; mechanism of chemical reactions in gas and condensed phases and at interfaces; chain and thermal processes of ignition, combustion and detonation in gases, two-phase and condensed systems; shock waves; new physical methods of examining chemical reactions; and biological processes in chemical physics.